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K-H_3OFe_3(SO_4)_2(OH)_6铁矾的XRD研究
许涛; 邹来昌; 阮仁满; 廖占丕; 苏秀珠; 苏妤芸; 黄丽娟
2013
Source Publication岩石矿物学杂志
Issue06Pages:995-1000
Abstract根据X射线衍射(XRD)分析发现:A Fe3(SO4)2(OH)6(A=K+、H3O+)系列铁钒的XRD数据十分相近,难以用XRD区别,需通过能谱(EDS)辅助分析,才能区分此类铁矾。另外,此类铁矾的003和107面网间距d随K+含量增大而增大,且呈一元三次方程的关系;而033和220面网间距d随K+含量增大而减小,呈一元二次方程的关系。对该现象从铁矾晶体结构方面进行解释:K+、H3O+离子位于较大空隙中,且沿着Z轴方向排列,当K+、H3O+离子之间相互替换时,会导致该铁矾晶体结构在Z轴方向有较明显的变化。
Keyword铁矾 Xrd 晶体结构 鉴别
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/10603
Collection研究所(批量导入)
Recommended Citation
GB/T 7714
许涛,邹来昌,阮仁满,等. K-H_3OFe_3(SO_4)_2(OH)_6铁矾的XRD研究[J]. 岩石矿物学杂志,2013(06):995-1000.
APA 许涛.,邹来昌.,阮仁满.,廖占丕.,苏秀珠.,...&黄丽娟.(2013).K-H_3OFe_3(SO_4)_2(OH)_6铁矾的XRD研究.岩石矿物学杂志(06),995-1000.
MLA 许涛,et al."K-H_3OFe_3(SO_4)_2(OH)_6铁矾的XRD研究".岩石矿物学杂志 .06(2013):995-1000.
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