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3-庚酮+乙酸乙酯、3-庚酮+乙酸丁酯、3-庚酮+TBP、MIBK+TBP二元体系的过量摩尔体积和黏度
杨得岭; 林晓; 曹宏斌; 李以圭; 张懿
2012
Source Publication化工学报
Issue08Pages:2327-2340
Abstract常压下测定了3-庚酮+乙酸乙酯、3-庚酮+乙酸丁酯、3-庚酮+磷酸三丁酯(TBP)、4-甲基-2-戊酮(MI-BK)+磷酸三丁酯4个二元体系在293.15~318.15K下的密度和黏度值,计算了二元体系的过量摩尔体积VE和过量黏度Δη,并用Redlich-Kister方程对VE和Δη进行了关联。混合溶剂的黏度数据采用Orrick-Erbar(O-E)基团贡献法进行了关联和预测,增加了O-E方法中的(—O)3—PO基团贡献值。结果表明,O-E方法可根据现有的纯溶剂的黏度数据预测得到混合溶剂的黏度,平均误差小于15%。
Keyword3-庚酮 磷酸三丁酯 4-甲基-2-戊酮 乙酸乙酯 乙酸丁酯 密度 黏度 Orrick-erbar(O-e)基团贡献法
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/10622
Collection研究所(批量导入)
Recommended Citation
GB/T 7714
杨得岭,林晓,曹宏斌,等. 3-庚酮+乙酸乙酯、3-庚酮+乙酸丁酯、3-庚酮+TBP、MIBK+TBP二元体系的过量摩尔体积和黏度[J]. 化工学报,2012(08):2327-2340.
APA 杨得岭,林晓,曹宏斌,李以圭,&张懿.(2012).3-庚酮+乙酸乙酯、3-庚酮+乙酸丁酯、3-庚酮+TBP、MIBK+TBP二元体系的过量摩尔体积和黏度.化工学报(08),2327-2340.
MLA 杨得岭,et al."3-庚酮+乙酸乙酯、3-庚酮+乙酸丁酯、3-庚酮+TBP、MIBK+TBP二元体系的过量摩尔体积和黏度".化工学报 .08(2012):2327-2340.
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