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以滑移机理探讨拖尾色谱峰与伸舌色谱峰
张大力; 柯家骏; 卢立柱
2009
Source Publication中国科技信息
Issue20Pages:29-30
Abstract本文以滑移机理研究"柱出口效应"失效的机制,以探讨伸舌色谱峰和拖尾色谱峰的形成机理。柱出口效应可使色谱流出峰变为拖尾峰。依据滑移机理,当温度升高使溶质吸附减弱和滑移作用增强时,柱出口效应可以减弱甚至失效。所以,塔板理论的色谱峰可以是拖尾形的,也可以是伸舌形的或高斯形。本文分析了克拉维酸钾的高效液相色谱流出峰由拖尾形经轻拖尾形、再到伸舌形的变化原因。
Keyword柱出口效应 拖尾峰 伸舌峰 塔板理论 滑移机理
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/10712
Collection研究所(批量导入)
Recommended Citation
GB/T 7714
张大力,柯家骏,卢立柱. 以滑移机理探讨拖尾色谱峰与伸舌色谱峰[J]. 中国科技信息,2009(20):29-30.
APA 张大力,柯家骏,&卢立柱.(2009).以滑移机理探讨拖尾色谱峰与伸舌色谱峰.中国科技信息(20),29-30.
MLA 张大力,et al."以滑移机理探讨拖尾色谱峰与伸舌色谱峰".中国科技信息 .20(2009):29-30.
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