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氯氧化铋在盐酸溶液中溶解度的测定和关联
张笛; 肖清贵; 张炳烛; 许永权; 徐红彬; 张懿
2014
Source Publication化工学报
Issue06Pages:1987-1992
Abstract在水解法制备氯氧化铋的反应结晶过程中,氯氧化铋在盐酸溶液中的溶解度数据至关重要。采用平衡法测定了303.15~363.15 K范围内氯氧化铋在盐酸溶液中的溶解度,并用Apelblat方程、经验多项式方程、λh方程对实验数据进行关联。结果表明:氯氧化铋溶解度随着盐酸浓度和温度的升高而增加,盐酸的浓度对氯氧化铋溶解度的影响更为显著;上述3种模型都可用于关联氯氧化铋的溶解度与温度的关系,就BiCl3-HCl-H2O体系而言,Apelblat方程、经验多项式方程和λh方程的拟合精度分别为0.99、0.98和0.93,Apelblat方程的模拟结果最佳。
Keyword氯氧化铋 溶解度 平衡法 关联
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/10715
Collection研究所(批量导入)
Recommended Citation
GB/T 7714
张笛,肖清贵,张炳烛,等. 氯氧化铋在盐酸溶液中溶解度的测定和关联[J]. 化工学报,2014(06):1987-1992.
APA 张笛,肖清贵,张炳烛,许永权,徐红彬,&张懿.(2014).氯氧化铋在盐酸溶液中溶解度的测定和关联.化工学报(06),1987-1992.
MLA 张笛,et al."氯氧化铋在盐酸溶液中溶解度的测定和关联".化工学报 .06(2014):1987-1992.
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