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Multinuclear Cobalt(II)-Containing Heteropolytungstates: Structure, Magnetism, and Electrochemistry
Alternative TitleInorg. Chem.
Ibrahim, Masooma1; Haider, Ali1; Lan, Yanhua3; Bassil, Bassem S.1; Carey, Akina M.1; Liu, Rongji4,5; Zhang, Guangjin4; Keita, Bineta6; Li, Wenhui4,8; Kostakis, George E.7; Powell, Annie K.2,3; Kortz, Ulrich1
2014-05-19
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume53Issue:10Pages:5179-5188
AbstractInteraction of the trilacunary Keggin polyanions [A-alpha-XW9O34](10-) (X = Si-IV, Ge-IV) with Co-II and phosphate ions in aqueous, basic media and under mild heating leads to the formation of the tetrameric, Co-16-containing heteropolytungstates [{Co-4(OH)(3)PO4}(4)(A-alpha-XW9O34)(4)](32-) (X = Si-IV, Ge-IV). Both polyanions were characterized in the solid state by single-crystal X-ray diffraction, IR spectroscopy, and thermogravirnetric and elemental analyses. Furthermore, the electrochemical and magnetic properties of these isostructural polyanions were investigated.; Interaction of the trilacunary Keggin polyanions [A-alpha-XW9O34](10-) (X = Si-IV, Ge-IV) with Co-II and phosphate ions in aqueous, basic media and under mild heating leads to the formation of the tetrameric, Co-16-containing heteropolytungstates [{Co-4(OH)(3)PO4}(4)(A-alpha-XW9O34)(4)](32-) (X = Si-IV, Ge-IV). Both polyanions were characterized in the solid state by single-crystal X-ray diffraction, IR spectroscopy, and thermogravirnetric and elemental analyses. Furthermore, the electrochemical and magnetic properties of these isostructural polyanions were investigated.
KeywordSingle-molecule Magnets Ferromagnetic Exchange Interactions Transition-metal Clusters Heptanuclear Cobalt(Ii) Cluster Inelastic Neutron-scattering Coordinated Water-molecules Crystal-structure Building-blocks Polyoxometalate Chemistry Hydrothermal Conditions
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1021/ic500298u
URL查看原文
Indexed BySCI
Language英语
WOS KeywordSINGLE-MOLECULE MAGNETS ; FERROMAGNETIC EXCHANGE INTERACTIONS ; TRANSITION-METAL CLUSTERS ; HEPTANUCLEAR COBALT(II) CLUSTER ; INELASTIC NEUTRON-SCATTERING ; COORDINATED WATER-MOLECULES ; CRYSTAL-STRUCTURE ; BUILDING-BLOCKS ; POLYOXOMETALATE CHEMISTRY ; HYDROTHERMAL CONDITIONS
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000336240400045
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/10917
Collection研究所(批量导入)
Affiliation1.Jacobs Univ Bremen, Sch Engn & Sci, D-28725 Bremen, Germany
2.Karlsruhe Inst Technol, Inst Nanotechnol INT, D-76344 Eggenstein Leopoldshafen, Germany
3.Karlsruhe Inst Technol, Inst Inorgan Chem, D-76131 Karlsruhe, Germany
4.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
6.Univ Paris 11, CNRS, UMR 8000, Lab Chim Phys,Grp Electrochim & Photoelectrochim, F-91405 Orsay, France
7.Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England
8.Jianghan Univ, Inst Interdisciplinary Res, Wuhan 430056, Hubei, Peoples R China
Recommended Citation
GB/T 7714
Ibrahim, Masooma,Haider, Ali,Lan, Yanhua,et al. Multinuclear Cobalt(II)-Containing Heteropolytungstates: Structure, Magnetism, and Electrochemistry[J]. INORGANIC CHEMISTRY,2014,53(10):5179-5188.
APA Ibrahim, Masooma.,Haider, Ali.,Lan, Yanhua.,Bassil, Bassem S..,Carey, Akina M..,...&Kortz, Ulrich.(2014).Multinuclear Cobalt(II)-Containing Heteropolytungstates: Structure, Magnetism, and Electrochemistry.INORGANIC CHEMISTRY,53(10),5179-5188.
MLA Ibrahim, Masooma,et al."Multinuclear Cobalt(II)-Containing Heteropolytungstates: Structure, Magnetism, and Electrochemistry".INORGANIC CHEMISTRY 53.10(2014):5179-5188.
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