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Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak
Alternative TitleJ. Mol. Struct.
Li, Xiaopei1,2,3; Fan, Xiaokun1,4; Huang, Kun1; Liu, Huizhou1; Zhao, Ying5; Wei, Yongju4; Liu, Cuige4; Xu, Yizhuang2; Noda, Isao6; Wu, Jinguang2
2014-07-08
Source PublicationJOURNAL OF MOLECULAR STRUCTURE
ISSN0022-2860
Volume1069Issue:1Pages:127-132
AbstractWe explore whether it is possible to use 2D correlation spectrum to characterize intermolecular interactions between two solutes dissolved in the same solution when one substance does not possesses any characteristic peak. We demonstrate that the interaction can be manifested by characteristic cross peaks in 2D asynchronous correlated spectrum. The above cross peaks reflect the subtle spectral variations on the characteristic peak of another solute under intermolecular interaction. On the other hand, 2D synchronous spectrum is not suitable to characterize intermolecular interaction since the cross peaks contain irremovable interfering parts. The terbium-chloride/benzamide/methanol system is used to demonstrate that this approach is applicable in the real chemical system. (C) 2014 Elsevier B.V. All rights reserved.; We explore whether it is possible to use 2D correlation spectrum to characterize intermolecular interactions between two solutes dissolved in the same solution when one substance does not possesses any characteristic peak. We demonstrate that the interaction can be manifested by characteristic cross peaks in 2D asynchronous correlated spectrum. The above cross peaks reflect the subtle spectral variations on the characteristic peak of another solute under intermolecular interaction. On the other hand, 2D synchronous spectrum is not suitable to characterize intermolecular interaction since the cross peaks contain irremovable interfering parts. The terbium-chloride/benzamide/methanol system is used to demonstrate that this approach is applicable in the real chemical system. (C) 2014 Elsevier B.V. All rights reserved.
KeywordTwo-dimensional Asynchronous Spectroscopy Intermolecular Interaction Asynchronous
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.molstruc.2014.01.046
URL查看原文
Indexed BySCI
Language英语
WOS Keyword2-DIMENSIONAL CORRELATION SPECTROSCOPY ; SAMPLE DESIGN SCHEME ; INFRARED CORRELATION ; IONIC-LIQUID ; METAL-IONS ; BEHAVIOR ; COORDINATION ; COMPLEXES ; MECHANISM ; CONJUNCTION
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000337989900015
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/10929
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China
5.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
6.Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA
Recommended Citation
GB/T 7714
Li, Xiaopei,Fan, Xiaokun,Huang, Kun,et al. Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak[J]. JOURNAL OF MOLECULAR STRUCTURE,2014,1069(1):127-132.
APA Li, Xiaopei.,Fan, Xiaokun.,Huang, Kun.,Liu, Huizhou.,Zhao, Ying.,...&Wu, Jinguang.(2014).Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak.JOURNAL OF MOLECULAR STRUCTURE,1069(1),127-132.
MLA Li, Xiaopei,et al."Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak".JOURNAL OF MOLECULAR STRUCTURE 1069.1(2014):127-132.
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