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Formation of C-C bonds for the production of bio-alkanes under mild conditions
Alternative TitleGreen Chem.
Xin, Jiayu1; Zhang, Suojiang1; Yan, Dongxia1; Ayodele, Olubunmi1; Lu, Xingmei1; Wang, Jianji2
2014
Source PublicationGREEN CHEMISTRY
ISSN1463-9262
Volume16Issue:7Pages:3589-3595
AbstractIt is of crucial importance to form C-C bonds between biomass-derived compounds for the production of bio-alkanes from biomass. In this study, it was found that C-C bonds can be formed between angelica lactones, key intermediates derived from biomass, through free radical reactions under mild conditions without using a noble catalyst or solvent, which gave elongated carbon chains of di/trimers with 10 or 15 carbons, with complete conversion and 100% selectivity. The di/trimers produced serve as a novel feed stock for the carbon backbones of bio-alkanes. Hydrogenation of the di/trimers produced C6-C13 hydrocarbons suitable for use as transportation fuels.; It is of crucial importance to form C-C bonds between biomass-derived compounds for the production of bio-alkanes from biomass. In this study, it was found that C-C bonds can be formed between angelica lactones, key intermediates derived from biomass, through free radical reactions under mild conditions without using a noble catalyst or solvent, which gave elongated carbon chains of di/trimers with 10 or 15 carbons, with complete conversion and 100% selectivity. The di/trimers produced serve as a novel feed stock for the carbon backbones of bio-alkanes. Hydrogenation of the di/trimers produced C6-C13 hydrocarbons suitable for use as transportation fuels.
KeywordCatalytic Conversion Lignocellulosic Biomass Formic-acid Transportation Fuels Gamma-valerolactone Levulinic Acid Chemicals Hydrodeoxygenation Hydrocarbons Cellulose
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c4gc00501e
URL查看原文
Indexed BySCI
Language英语
WOS KeywordCATALYTIC CONVERSION ; LIGNOCELLULOSIC BIOMASS ; FORMIC-ACID ; TRANSPORTATION FUELS ; GAMMA-VALEROLACTONE ; LEVULINIC ACID ; CHEMICALS ; HYDRODEOXYGENATION ; HYDROCARBONS ; CELLULOSE
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000338298600024
Citation statistics
Cited Times:50[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/10996
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
2.Henan Normal Univ, Sch Chem & Environm Sci, Minist Educ, Key Lab Green Chem Media & React, Xinxiang 453007, Henan, Peoples R China
Recommended Citation
GB/T 7714
Xin, Jiayu,Zhang, Suojiang,Yan, Dongxia,et al. Formation of C-C bonds for the production of bio-alkanes under mild conditions[J]. GREEN CHEMISTRY,2014,16(7):3589-3595.
APA Xin, Jiayu,Zhang, Suojiang,Yan, Dongxia,Ayodele, Olubunmi,Lu, Xingmei,&Wang, Jianji.(2014).Formation of C-C bonds for the production of bio-alkanes under mild conditions.GREEN CHEMISTRY,16(7),3589-3595.
MLA Xin, Jiayu,et al."Formation of C-C bonds for the production of bio-alkanes under mild conditions".GREEN CHEMISTRY 16.7(2014):3589-3595.
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