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Self-Assembly and Headgroup Effect in Nanostructured Organogels via Cationic Amphiphile-Graphene Oxide Composites
Alternative TitlePLoS One
Jiao, Tifeng1,2; Wang, Yujin1; Zhang, Qingrui1; Yan, Xuehai2; Zhao, Xiaoqing1; Zhou, Jingxin1; Gao, Faming1
2014-07-01
Source PublicationPLOS ONE
ISSN1932-6203
Volume9Issue:7Pages:11
AbstractSelf-assembly of hierarchical graphene oxide (GO)-based nanomaterials with novel functions has received a great deal of attentions. In this study, nanostructured organogels based on cationic amphiphile-GO composites were prepared. The gelation behaviors of amphiphile-GO composites in organic solvents can be regulated by changing the headgroups of amphiphiles. Ammonium substituted headgroup in molecular structures in present self-assembled composites is more favorable for the gelation in comparison to pyridinium headgroup. A possible mechanism for headgroup effects on self-assembly and as-prepared nanostructures is proposed. It is believed that the present amphiphile-GO self-assembled system will provide an alternative platform for the design of new GO nanomaterials and soft matters.; Self-assembly of hierarchical graphene oxide (GO)-based nanomaterials with novel functions has received a great deal of attentions. In this study, nanostructured organogels based on cationic amphiphile-GO composites were prepared. The gelation behaviors of amphiphile-GO composites in organic solvents can be regulated by changing the headgroups of amphiphiles. Ammonium substituted headgroup in molecular structures in present self-assembled composites is more favorable for the gelation in comparison to pyridinium headgroup. A possible mechanism for headgroup effects on self-assembly and as-prepared nanostructures is proposed. It is believed that the present amphiphile-GO self-assembled system will provide an alternative platform for the design of new GO nanomaterials and soft matters.
KeywordSensitized Solar-cells Graphite Oxide Polymer Nanocomposites Chemical-reduction Imide Derivatives Ionic Liquids Hydrogels Nanosheets Fabrication Supercapacitors
SubtypeArticle
WOS HeadingsScience & Technology
DOI10.1371/journal.pone.0101620
URL查看原文
Indexed BySCI
Language英语
WOS KeywordSENSITIZED SOLAR-CELLS ; GRAPHITE OXIDE ; POLYMER NANOCOMPOSITES ; CHEMICAL-REDUCTION ; IMIDE DERIVATIVES ; IONIC LIQUIDS ; HYDROGELS ; NANOSHEETS ; FABRICATION ; SUPERCAPACITORS
WOS Research AreaScience & Technology - Other Topics
WOS SubjectMultidisciplinary Sciences
WOS IDWOS:000339635000125
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/11333
Collection研究所(批量导入)
Affiliation1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Jiao, Tifeng,Wang, Yujin,Zhang, Qingrui,et al. Self-Assembly and Headgroup Effect in Nanostructured Organogels via Cationic Amphiphile-Graphene Oxide Composites[J]. PLOS ONE,2014,9(7):11.
APA Jiao, Tifeng.,Wang, Yujin.,Zhang, Qingrui.,Yan, Xuehai.,Zhao, Xiaoqing.,...&Gao, Faming.(2014).Self-Assembly and Headgroup Effect in Nanostructured Organogels via Cationic Amphiphile-Graphene Oxide Composites.PLOS ONE,9(7),11.
MLA Jiao, Tifeng,et al."Self-Assembly and Headgroup Effect in Nanostructured Organogels via Cationic Amphiphile-Graphene Oxide Composites".PLOS ONE 9.7(2014):11.
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