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Hofmeister Ion Series and Its Mechanism of Action on Affecting the Behavior of Macromolecular Solutes in Aqueous Solution
Alternative TitleProg. Chem.
Li Xiaopei1,2; Huang Kun1; Lin Jieyuan1,2; Xu Yizhuang3; Liu Huizhou1
2014-08-01
Source PublicationPROGRESS IN CHEMISTRY
ISSN1005-281X
Volume26Issue:8Pages:1285-1291
AbstractHofmeister ion series is ubiquitous and turns up frequently in many chemical and biological processes. The explanations for its mechanism of action on target macromolecules in aqueous solutions fall into two categories. The first one states that ions affect the behavior of macromolecular solutes in the aqueous solution by interacting with water, while the other one claims that direct interactions between ions and macromolecules are the key point for comprehending the Hofmeister ion series. In this paper, research works on the two mechanisms of action are elaborately reviewed. In fact, actual solution systems are inevitably complicated by rather delicate balance of all the interactions (e. g., water-water, water-ion, water-solute, ion-solute, cation-anion) and the above mentioned two viewpoints explain the Hofmeister ion series just from one side. More work is still needed to dig into the secret behind the Hofmeister ion series.; Hofmeister ion series is ubiquitous and turns up frequently in many chemical and biological processes. The explanations for its mechanism of action on target macromolecules in aqueous solutions fall into two categories. The first one states that ions affect the behavior of macromolecular solutes in the aqueous solution by interacting with water, while the other one claims that direct interactions between ions and macromolecules are the key point for comprehending the Hofmeister ion series. In this paper, research works on the two mechanisms of action are elaborately reviewed. In fact, actual solution systems are inevitably complicated by rather delicate balance of all the interactions (e. g., water-water, water-ion, water-solute, ion-solute, cation-anion) and the above mentioned two viewpoints explain the Hofmeister ion series just from one side. More work is still needed to dig into the secret behind the Hofmeister ion series.
KeywordHofmeister Ion Series Kosmotropic Ions Chaotropic Ions Macromolecules Mechanism Of Action
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.7536/PC140436
URL查看原文
Indexed BySCI
Language英语
WOS KeywordINTERFACIAL WATER-STRUCTURE ; HYDROGEN-BOND STRUCTURE ; POLY(ETHYLENE OXIDE) ; DISPERSION FORCES ; FTIR SPECTROSCOPY ; BLOCK-COPOLYMER ; SURFACE-TENSION ; LIQUID WATER ; SALTING-OUT ; MICELLIZATION
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000341282900002
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/11452
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Li Xiaopei,Huang Kun,Lin Jieyuan,et al. Hofmeister Ion Series and Its Mechanism of Action on Affecting the Behavior of Macromolecular Solutes in Aqueous Solution[J]. PROGRESS IN CHEMISTRY,2014,26(8):1285-1291.
APA Li Xiaopei,Huang Kun,Lin Jieyuan,Xu Yizhuang,&Liu Huizhou.(2014).Hofmeister Ion Series and Its Mechanism of Action on Affecting the Behavior of Macromolecular Solutes in Aqueous Solution.PROGRESS IN CHEMISTRY,26(8),1285-1291.
MLA Li Xiaopei,et al."Hofmeister Ion Series and Its Mechanism of Action on Affecting the Behavior of Macromolecular Solutes in Aqueous Solution".PROGRESS IN CHEMISTRY 26.8(2014):1285-1291.
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