CAS OpenIR  > 研究所(批量导入)
Structure, Interaction and Hydrogen Bond
Alternative TitleStruct. Bond.
Dong, Kun2; Wang, Qian2; Lu, Xingmei2; Zhou, Qing2; Zhang, Suojiang2; Zhang, S; Wang, J; Lu, X; Zhou, Q
2014
Source PublicationSTRUCTURES AND INTERACTIONS OF IONIC LIQUIDS
ISSN0081-5993
Volume151Issue:BPages:1-38
AbstractIonic liquids (ILs), as green solvents, have attracted amazing interest and their potential applications have prompted a large amount of research and investment, and some of the results have been inspiring. In recent years, in combination with cations and anions, some new ILs have been synthesized in the laboratory. However, compared with simple solid salts, the structures of ILs are complicated and their properties vary considerably. It is thus very time consuming to explore ILs experimentally when facing the huge number of ionic combinations. A molecular-based understanding can reveal the quantitative correlation between structures and properties, and is thus an important subject in the study of ILs. The unusual complexity of ionic interactions renders molecular-based interpretations difficult and gives rise to controversies about the structure of the ILs. Herein we discuss the ion-pair, cluster and X-ray crystals structures and their relationship with the properties of many typical ILs, especially imidazolium-based. In the ILs, apart from the strong electrostatic forces, non-covalent H-bonds and van der Waals (dispersion, induce forces) are examined and are shown to have a decisive effect on the properties of ILs.; Ionic liquids (ILs), as green solvents, have attracted amazing interest and their potential applications have prompted a large amount of research and investment, and some of the results have been inspiring. In recent years, in combination with cations and anions, some new ILs have been synthesized in the laboratory. However, compared with simple solid salts, the structures of ILs are complicated and their properties vary considerably. It is thus very time consuming to explore ILs experimentally when facing the huge number of ionic combinations. A molecular-based understanding can reveal the quantitative correlation between structures and properties, and is thus an important subject in the study of ILs. The unusual complexity of ionic interactions renders molecular-based interpretations difficult and gives rise to controversies about the structure of the ILs. Herein we discuss the ion-pair, cluster and X-ray crystals structures and their relationship with the properties of many typical ILs, especially imidazolium-based. In the ILs, apart from the strong electrostatic forces, non-covalent H-bonds and van der Waals (dispersion, induce forces) are examined and are shown to have a decisive effect on the properties of ILs.
KeywordIonic Liquid Structure Interaction Property Application
SubtypeReview
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1007/978-3-642-38619-0_1
URL查看原文
Indexed BySCI
Language英语
WOS KeywordTEMPERATURE IONIC LIQUIDS ; MOLECULAR-DYNAMICS SIMULATION ; DIELS-ALDER REACTIONS ; X-RAY-DIFFRACTION ; MOLTEN-SALTS ; CRYSTAL-STRUCTURES ; 1-N-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE ; PHYSICOCHEMICAL PROPERTIES ; PHYSICAL-PROPERTIES ; INITIO CALCULATIONS
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Physical
WOS IDWOS:000344737400002
PublisherSpringer-Verlag Berlin
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/11725
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Ion Liquids Clean Proc,Key Lab Green Proc, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Dong, Kun,Wang, Qian,Lu, Xingmei,et al. Structure, Interaction and Hydrogen Bond[J]. STRUCTURES AND INTERACTIONS OF IONIC LIQUIDS,2014,151(B):1-38.
APA Dong, Kun.,Wang, Qian.,Lu, Xingmei.,Zhou, Qing.,Zhang, Suojiang.,...&Zhou, Q.(2014).Structure, Interaction and Hydrogen Bond.STRUCTURES AND INTERACTIONS OF IONIC LIQUIDS,151(B),1-38.
MLA Dong, Kun,et al."Structure, Interaction and Hydrogen Bond".STRUCTURES AND INTERACTIONS OF IONIC LIQUIDS 151.B(2014):1-38.
Files in This Item:
File Name/Size DocType Version Access License
Structure, Interacti(7308KB)期刊论文出版稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Dong, Kun]'s Articles
[Wang, Qian]'s Articles
[Lu, Xingmei]'s Articles
Baidu academic
Similar articles in Baidu academic
[Dong, Kun]'s Articles
[Wang, Qian]'s Articles
[Lu, Xingmei]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Dong, Kun]'s Articles
[Wang, Qian]'s Articles
[Lu, Xingmei]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.