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Influence of FeCl3 on radiation stability of ionic liquid BmimCl
Huang Lei1,2; Huang Wei1; Fu HaiYing1; Wu GuoZhong1; Guo ZhiJun2; Wu WangSuo2; Chen ShiMou3
2013-04-01
Source PublicationCHINESE SCIENCE BULLETIN
ISSN1001-6538
Volume58Issue:10Pages:1150-1155
AbstractThis study investigates the effect FeCl3 on the radiation stability of the ionic liquid, 1-butyl-3-methylimidazolium chloride (BmimCl) over a wide dose range of 0 to 1000 kGy under gamma-ray radiation. The ionic liquid species, BmimFeCl(4), was formed by adding FeCl3 into BmimCl. The results showed that the presence of FeCl4 (-) significantly improved the radiation resistance of BmimCl, wherein the effect was more pronounced at higher FeCl4 (-) content. Meanwhile, under irradiation, Fe(II) was generated from Fe(III), which was reduced by solvated electron. In addition, the concentration of Fe(II) increased with low level of absorbed dose, but leveled off at higher doses. Moreover, the radiation yield of the solvated electrons of BmimCl was further estimated at approximately 0.358 +/- 0.01 mu mol/J in BmimCl-7 mol% FeCl3 system.
KeywordRadiation Ionic Liquid Fecl3 Bmimfecl(4) Solvated Electron
SubtypeArticle
WOS HeadingsScience & Technology
DOI10.1007/s11434-012-5656-3
Indexed BySCI
Language英语
WOS KeywordROOM-TEMPERATURE ; SOLVATED ELECTRON ; GAMMA-RADIATION ; RADIOLYSIS
WOS Research AreaScience & Technology - Other Topics
WOS SubjectMultidisciplinary Sciences
WOS IDWOS:000316954900009
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/13408
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
2.Lanzhou Univ, Sch Nucl Sci & Technol, Radiochem Lab, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Huang Lei,Huang Wei,Fu HaiYing,et al. Influence of FeCl3 on radiation stability of ionic liquid BmimCl[J]. CHINESE SCIENCE BULLETIN,2013,58(10):1150-1155.
APA Huang Lei.,Huang Wei.,Fu HaiYing.,Wu GuoZhong.,Guo ZhiJun.,...&Chen ShiMou.(2013).Influence of FeCl3 on radiation stability of ionic liquid BmimCl.CHINESE SCIENCE BULLETIN,58(10),1150-1155.
MLA Huang Lei,et al."Influence of FeCl3 on radiation stability of ionic liquid BmimCl".CHINESE SCIENCE BULLETIN 58.10(2013):1150-1155.
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