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Enzymatic synthesis of oleic acid-based epoxy monomer for the production of value added polymers | |
Miao, Shida1,2; Callow, Nicholas2; Zhang, Songping1; Su, Zhiguo1; Wang, Ping3; Liu, Youyan4 | |
2013-06-01 | |
Source Publication | BIOTECHNOLOGY LETTERS
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Volume | 35Issue:6Pages:887-890 |
Abstract | An oleic acid-based epoxy monomer was synthesized by reacting 2-hydroxyethyl acrylate with epoxy stearic acid and an immobilized lipase. NMR, electrospray ionization mass spectrometry and gel permeation chromatography were used to characterize the intermediates and products. 2-(Acryloyloxy) ethyl epoxy stearate was synthesized with a yield of 87 % w/w. After free radical polymerization, epoxy stearic acid-grafted epoxy polymer with molecular weight of 15,150 g/mol was obtained; the final yield was 81 % w/w. |
Keyword | Epoxy Stearic Acid Fatty Acid Lipase Monomer Oleic Acid Polymer |
Subtype | Article |
WOS Headings | Science & Technology ; Life Sciences & Biomedicine |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | RESINS |
WOS Research Area | Biotechnology & Applied Microbiology |
WOS Subject | Biotechnology & Applied Microbiology |
WOS ID | WOS:000319427500007 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/13433 |
Collection | 研究所(批量导入) |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China 2.Univ Akron, Dept Chem & Biomol Engn, Akron, OH 44325 USA 3.Univ Minnesota, Inst Biotechnol, Dept Bioprod & Biosyst Engn, St Paul, MN 55108 USA 4.Guangxi Univ, Guangxi Key Lab Biorefinery, Nanning 530004, Peoples R China |
Recommended Citation GB/T 7714 | Miao, Shida,Callow, Nicholas,Zhang, Songping,et al. Enzymatic synthesis of oleic acid-based epoxy monomer for the production of value added polymers[J]. BIOTECHNOLOGY LETTERS,2013,35(6):887-890. |
APA | Miao, Shida,Callow, Nicholas,Zhang, Songping,Su, Zhiguo,Wang, Ping,&Liu, Youyan.(2013).Enzymatic synthesis of oleic acid-based epoxy monomer for the production of value added polymers.BIOTECHNOLOGY LETTERS,35(6),887-890. |
MLA | Miao, Shida,et al."Enzymatic synthesis of oleic acid-based epoxy monomer for the production of value added polymers".BIOTECHNOLOGY LETTERS 35.6(2013):887-890. |
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Enzymatic synthesis (294KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text |
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