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Synthesis of substituted meso-tetraphenylporphyrins in mixed solvent systems
Sun, Zhicheng1,2; She, Yuanbin1; Cao, Meijuan1; Zhou, Qing2; Lu, Xingmei2; Zhang, Suojiang2
2013
Source PublicationARKIVOC
Issue0Pages:389-400
AbstractAn efficient synthetic method of substituted meso-tetraphenylporphyrins with better isolated yields was proposed by using propionic acid, valeric acid and m-nitrotoluene as mixed-solvent systems. The porphyrin yields in mixed solvent systems were obviously higher than those in the single propionic acid or valeric acid as solvents. The further investigation showed that the acidity, polarity, viscosity and the property of oxidant played an important role to the synthesis of porphyrin. Compared with other oxidants, m-nitrotoluene as an excellent oxidant could completely transform tetraphenylporphyrinogen to tetraphenylporphyrin.
KeywordPorphyrin Synthesis Mixed Solvents Oxidant
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
Indexed BySCI
Language英语
WOS KeywordMESOSUBSTITUTED CORROLES ; PORPHYRINS ; OXIDATION ; LIGAND ; ROTHEMUND ; CATALYSTS ; PYRROLE ; 2-STEP ; SALTS ; AIR
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
WOS IDWOS:000324461400027
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/13603
Collection研究所(批量导入)
Affiliation1.Beijing Univ Technol, Inst Green Chem & Fine Chem, Beijing 100124, Peoples R China
2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Sun, Zhicheng,She, Yuanbin,Cao, Meijuan,et al. Synthesis of substituted meso-tetraphenylporphyrins in mixed solvent systems[J]. ARKIVOC,2013(0):389-400.
APA Sun, Zhicheng,She, Yuanbin,Cao, Meijuan,Zhou, Qing,Lu, Xingmei,&Zhang, Suojiang.(2013).Synthesis of substituted meso-tetraphenylporphyrins in mixed solvent systems.ARKIVOC(0),389-400.
MLA Sun, Zhicheng,et al."Synthesis of substituted meso-tetraphenylporphyrins in mixed solvent systems".ARKIVOC .0(2013):389-400.
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