CAS OpenIR  > 研究所(批量导入)
Ionic liquid enhanced alkylation of iso-butane and 1-butene
Cui, Peng1,2; Zhao, Guoying2; Ren, Hailing1,2; Huang, Jun1; Zhang, Suojiang2
2013-02-01
Source PublicationCATALYSIS TODAY
Volume200Issue:0Pages:30-35
AbstractThe alkylation of iso-butane with 1-butene was catalyzed by triflic acid (TFOH) coupled with a series of protic ammonium-based ionic liquids (AMILs), and the addition of the AMILs dramatically enhanced the efficiency of TFOH for the alkylation reaction. Up to 85.1% trimethylpentanes (TMP) selectivity and 98 research octane number (RON) were achieved with the optimized TFOH/AMIL catalyst ( 75 vol.% triflic acid and 25 vol.% triethylammonium hydrogen sulfate), which were much better than that with the commercial H2SO4 catalyst (65% TMP selectivity, 97 RON) and pure triflic acid. The addition of AMILs increased the I/O ratio dissolved in the catalyst system and adjusted the acidity of the TFOH/AMILs catalyst system, which were highly beneficial to the alkylation reaction and resulted in high TMP selectivity and high RON. (c) 2012 Elsevier B.V. All rights reserved.
KeywordIonic Liquids Alkylation Iso-butane Butene Triflic Acid
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
Indexed BySCI
Language英语
WOS KeywordSOLID ACID CATALYSTS ; ISOBUTANE ALKYLATION ; 2-BUTENE ; SOLUBILITIES ; DIFFUSIVITY ; BUTENE ; MEDIA
WOS Research AreaChemistry ; Engineering
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS IDWOS:000311938100006
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/13620
Collection研究所(批量导入)
Affiliation1.Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn,Beijing Key Lab Ion Liquids Clean, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ionic Liquids Clean Proc, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Cui, Peng,Zhao, Guoying,Ren, Hailing,et al. Ionic liquid enhanced alkylation of iso-butane and 1-butene[J]. CATALYSIS TODAY,2013,200(0):30-35.
APA Cui, Peng,Zhao, Guoying,Ren, Hailing,Huang, Jun,&Zhang, Suojiang.(2013).Ionic liquid enhanced alkylation of iso-butane and 1-butene.CATALYSIS TODAY,200(0),30-35.
MLA Cui, Peng,et al."Ionic liquid enhanced alkylation of iso-butane and 1-butene".CATALYSIS TODAY 200.0(2013):30-35.
Files in This Item:
File Name/Size DocType Version Access License
Ionic liquid enhance(801KB)期刊论文出版稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Cui, Peng]'s Articles
[Zhao, Guoying]'s Articles
[Ren, Hailing]'s Articles
Baidu academic
Similar articles in Baidu academic
[Cui, Peng]'s Articles
[Zhao, Guoying]'s Articles
[Ren, Hailing]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Cui, Peng]'s Articles
[Zhao, Guoying]'s Articles
[Ren, Hailing]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.