Investigating the Multiple Roles of Polyvinylpyrrolidone for a General Methodology of Oxide Encapsulation

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	Investigating the Multiple Roles of Polyvinylpyrrolidone for a General Methodology of Oxide Encapsulation
	Sun, Hang 1; He, Jiating 1; Wang, Jiangyan 2; Zhang, Shuang-Yuan 4; Liu, Cuicui 1; Sritharan, Thirumany 3,5; Mhaisalkar, Subodh 3,5; Han, Ming-Yong 4; Wang, Dan 2; Chen, Hongyu 1,5
	2013-06-19
Source Publication	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume	135 Issue:24 Pages:9099-9110
Abstract	Growing oxide shells on seed nanoparticles requires the control of several processes: (a) the nucleation and growth of the shell material; (b) the "wetting" of the shell material on the seeds; and (c) the aggregation of the nanoparticles. These processes are influenced by a number of factors, many of which are related. Without understanding the interdependence of these contributing factors, it is difficult to circumvent problems and achieve rational synthesis. We first did a case study on encapsulating Au nanoparticles with ZnO to understand the multiple roles of polyvinylpyrrolidone (PVP) and their dependence on other factors. We developed a general method for coating ZnO on a variety of seeds, including metals, oxides, polymer nanoparticles, graphene oxide, and carbon nanotube. This method can be further extended to include Fe3O4, MnO, Co2O3, TiO2, Eu2O3, Tb2O3, Gd2O3, beta-Ni(OH)(2), ZnS, and CdS as the shell materials. The understanding obtained in this systematic study will aid rational design and synthesis of other core-shell nanostructures.
Subtype	Article
WOS Headings	Science & Technology ; Physical Sciences
Indexed By	SCI
Language	英语
WOS Keyword	ENHANCED RAMAN-SCATTERING ; CORE-SHELL NANOPARTICLES ; OPTICAL-PROPERTIES ; METAL NANOCRYSTALS ; EPITAXIAL-GROWTH ; FACILE SYNTHESIS ; NANOSTRUCTURES ; AU ; SEMICONDUCTOR ; PARTICLES
WOS Research Area	Chemistry
WOS Subject	Chemistry, Multidisciplinary
WOS ID	WOS:000320899200050
Citation statistics	Cited Times:143[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.ipe.ac.cn/handle/122111/13659
Collection	研究所（批量导入）
Affiliation	1.Nanyang Technol Univ, Div Chem & Biol Chem, Singapore 637371, Singapore 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore 4.Agcy Sci Technol & Res, Inst Mat Res & Engn, Singapore 117602, Singapore 5.Singapore Berkeley Res Initiat Sustainable Energy, Singapore 138602, Singapore
Recommended Citation GB/T 7714	Sun, Hang,He, Jiating,Wang, Jiangyan,et al. Investigating the Multiple Roles of Polyvinylpyrrolidone for a General Methodology of Oxide Encapsulation[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2013,135(24):9099-9110.
APA	Sun, Hang.,He, Jiating.,Wang, Jiangyan.,Zhang, Shuang-Yuan.,Liu, Cuicui.,...&Chen, Hongyu.(2013).Investigating the Multiple Roles of Polyvinylpyrrolidone for a General Methodology of Oxide Encapsulation.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,135(24),9099-9110.
MLA	Sun, Hang,et al."Investigating the Multiple Roles of Polyvinylpyrrolidone for a General Methodology of Oxide Encapsulation".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 135.24(2013):9099-9110.

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