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Study on Short, Straight Alkyl Chain Substituted Dithiophosphinic Acids for Actinides and Lanthanides Extraction Separation
Wang, Fang1,3; Jia, Cai2; Pan, Dengfang1; Chen, Jing1
2013-12-25
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume52Issue:51Pages:18373-18378
AbstractTwo short, straight alkyl chain substituted dithiophosphinic acids were investigated as extractant candidates for actinides (An) and lanthanides (Ln) separation. The extraction and separation performance by di-n-pentyl dithiophosphinic acid for Am3+ and Eu3+ was very attracrive and comparable to Cyanex 301. The radiation effect on Am3+ and Eu3+ extraction of di-n-pentyldithiophosphinic acid was investigated. The chemical stability and radiation stability of the two dithiophosphinic acids were also examined. Di-n-pentyldithiophosphinic acid which is of 35% higher gravimetric An loading than purified Cyanex 301 was proven a potential candidate for industrial-scale An and Ln extraction separation.
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
Indexed BySCI
Language英语
WOS KeywordPURIFIED CYANEX 301 ; BIS(2,4,4-TRIMETHYLPENTYL)DITHIOPHOSPHINIC ACID ; DIALKYLDITHIOPHOSPHINIC ACID ; SELECTIVE EXTRACTION ; TRIVALENT ACTINIDES ; SPECTROSCOPY ; COMPLEXES ; AM(III) ; AMERICIUM ; CHEMISTRY
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
WOS IDWOS:000329137500026
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/13686
Collection研究所(批量导入)
Affiliation1.Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China
2.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
3.Natl Univ Def Technol, Coll Sci, Changsha 410073, Hunan, Peoples R China
Recommended Citation
GB/T 7714
Wang, Fang,Jia, Cai,Pan, Dengfang,et al. Study on Short, Straight Alkyl Chain Substituted Dithiophosphinic Acids for Actinides and Lanthanides Extraction Separation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2013,52(51):18373-18378.
APA Wang, Fang,Jia, Cai,Pan, Dengfang,&Chen, Jing.(2013).Study on Short, Straight Alkyl Chain Substituted Dithiophosphinic Acids for Actinides and Lanthanides Extraction Separation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,52(51),18373-18378.
MLA Wang, Fang,et al."Study on Short, Straight Alkyl Chain Substituted Dithiophosphinic Acids for Actinides and Lanthanides Extraction Separation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 52.51(2013):18373-18378.
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