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Study on Short, Straight Alkyl Chain Substituted Dithiophosphinic Acids for Actinides and Lanthanides Extraction Separation | |
Wang, Fang1,3; Jia, Cai2; Pan, Dengfang1; Chen, Jing1 | |
2013-12-25 | |
Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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Volume | 52Issue:51Pages:18373-18378 |
Abstract | Two short, straight alkyl chain substituted dithiophosphinic acids were investigated as extractant candidates for actinides (An) and lanthanides (Ln) separation. The extraction and separation performance by di-n-pentyl dithiophosphinic acid for Am3+ and Eu3+ was very attracrive and comparable to Cyanex 301. The radiation effect on Am3+ and Eu3+ extraction of di-n-pentyldithiophosphinic acid was investigated. The chemical stability and radiation stability of the two dithiophosphinic acids were also examined. Di-n-pentyldithiophosphinic acid which is of 35% higher gravimetric An loading than purified Cyanex 301 was proven a potential candidate for industrial-scale An and Ln extraction separation. |
Subtype | Article |
WOS Headings | Science & Technology ; Technology |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | PURIFIED CYANEX 301 ; BIS(2,4,4-TRIMETHYLPENTYL)DITHIOPHOSPHINIC ACID ; DIALKYLDITHIOPHOSPHINIC ACID ; SELECTIVE EXTRACTION ; TRIVALENT ACTINIDES ; SPECTROSCOPY ; COMPLEXES ; AM(III) ; AMERICIUM ; CHEMISTRY |
WOS Research Area | Engineering |
WOS Subject | Engineering, Chemical |
WOS ID | WOS:000329137500026 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/13686 |
Collection | 研究所(批量导入) |
Affiliation | 1.Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 3.Natl Univ Def Technol, Coll Sci, Changsha 410073, Hunan, Peoples R China |
Recommended Citation GB/T 7714 | Wang, Fang,Jia, Cai,Pan, Dengfang,et al. Study on Short, Straight Alkyl Chain Substituted Dithiophosphinic Acids for Actinides and Lanthanides Extraction Separation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2013,52(51):18373-18378. |
APA | Wang, Fang,Jia, Cai,Pan, Dengfang,&Chen, Jing.(2013).Study on Short, Straight Alkyl Chain Substituted Dithiophosphinic Acids for Actinides and Lanthanides Extraction Separation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,52(51),18373-18378. |
MLA | Wang, Fang,et al."Study on Short, Straight Alkyl Chain Substituted Dithiophosphinic Acids for Actinides and Lanthanides Extraction Separation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 52.51(2013):18373-18378. |
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Study on Short, Stra(1070KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text |
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