CAS OpenIR  > 研究所(批量导入)
Triethanolamine/KI: A Multifunctional Catalyst for CO2 Activation and Conversion with Epoxides into Cyclic Carbonates
Xiao, Benneng1; Sun, Jian2; Wang, Jinquan2; Liu, Chunyan1; Cheng, Weiguo2
2013-11-17
Source PublicationSYNTHETIC COMMUNICATIONS
Volume43Issue:22Pages:2985-2997
AbstractA catalytic system of triethanolamine/potassium iodide (KI) was proved to be efficient for the chemical fixation of CO2 with epoxide. It was found that triethanolamine with dual function could activate both CO2 and epoxides. Effects of parameters such as catalyst molar ratio and amount, reaction time, pressure, and temperature were studied systematically. As a result, 99% propylene oxide conversion as well as 99% propylene carbonate selectivity could be obtained under the optimal reaction condition. Furthermore, the catalyst was found to be applicable to a variety of terminal epoxides, providing the corresponding cyclic carbonates in good yields and selectivity. Moreover, the catalyst could be reused five times without loss of activity. This work presents an example of a cheap and efficient catalyst for the chemical fixation of CO2 to high-value chemicals, which could help to improve the catalytic efficiency and decrease cost of products for larger applications. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource: Full experimental and spectral details.]
KeywordCarbon Dioxide Chemical Fixation Cyclic Carbonates Ki Triethanolamine
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
Indexed BySCI
Language英语
WOS KeywordFUNCTIONALIZED IONIC LIQUID ; CHEMICAL FIXATION ; PROPYLENE CARBONATE ; DIMETHYL CARBONATE ; ORGANIC CARBONATES ; SMECTITE CATALYSTS ; SALEN COMPLEXES ; BASE CATALYSTS ; ETHYLENE-OXIDE ; DIOXIDE
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
WOS IDWOS:000322865800003
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/13739
Collection研究所(批量导入)
Affiliation1.Liaoning Normal Univ, Sch Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Xiao, Benneng,Sun, Jian,Wang, Jinquan,et al. Triethanolamine/KI: A Multifunctional Catalyst for CO2 Activation and Conversion with Epoxides into Cyclic Carbonates[J]. SYNTHETIC COMMUNICATIONS,2013,43(22):2985-2997.
APA Xiao, Benneng,Sun, Jian,Wang, Jinquan,Liu, Chunyan,&Cheng, Weiguo.(2013).Triethanolamine/KI: A Multifunctional Catalyst for CO2 Activation and Conversion with Epoxides into Cyclic Carbonates.SYNTHETIC COMMUNICATIONS,43(22),2985-2997.
MLA Xiao, Benneng,et al."Triethanolamine/KI: A Multifunctional Catalyst for CO2 Activation and Conversion with Epoxides into Cyclic Carbonates".SYNTHETIC COMMUNICATIONS 43.22(2013):2985-2997.
Files in This Item:
File Name/Size DocType Version Access License
Triethanolamine KI- (366KB)期刊论文出版稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Xiao, Benneng]'s Articles
[Sun, Jian]'s Articles
[Wang, Jinquan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Xiao, Benneng]'s Articles
[Sun, Jian]'s Articles
[Wang, Jinquan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Xiao, Benneng]'s Articles
[Sun, Jian]'s Articles
[Wang, Jinquan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.