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Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metal ions
Gao, Dan-Qing1,2; Li, Xiao-Pei2,3,4; Shi, Jia-Jia2,5; Kang, Xiao-Yan1,2; Kang, Ting-Guo1; Xia, Jin-Ming6; Ling, Xiao-Feng7; Weng, Shi-Fu2; Xu, Yi-Zhuang2,8; Noda, Isao2,9; Wu, Jin-Guang2
2015-02-01
Source PublicationCHINESE CHEMICAL LETTERS
ISSN1001-8417
Volume26Issue:2Pages:177-181
Abstract

Two dimensional asynchronous spectra were used to characterize coordination between carbonyl group of butanone and metal ions by using an approach proposed in our recent paper. Spectral variation of n-pi* transition band of carbonyl group is used to probe the coordination even if metal ions does not possess any characteristic peak in spectra. Experimental results indicate that Ca2+ and Al3+ show considerable ability to coordinate with the carbonyl group of butanone and bring about spectral variation of the n-pi* transition band, which is manifested by cross peaks in 2D asynchronous spectra. (C) 2015 Ting-Guo Kang and Yi-Zhuang Xu. Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. All rights reserved.

KeywordCa2++++ Al3++++ Butanone Coordination 2d Correlation Spectroscopy
SubtypeArticle
Subject AreaChemistry
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.cclet.2015.01.013
Indexed BySCI
Language英语
WOS KeywordSample Design Scheme ; Probing Intermolecular Interactions ; Dipole-dipole Interactions ; Asynchronous Spectroscopy ; Synchronous Spectroscopy ; Solution Mixtures ; Lanthanide Ions ; Daosd Approach ; Lithium-salts ; Aosd Approach
Funding ProjectNational Natural Science Foundation of China [51373003] ; Beijing Natural Science Foundation [2122059]
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000351649200003
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/13827
Collection研究所(批量导入)
Corresponding AuthorKang, Ting-Guo
Affiliation1.Liaoning Univ Tradit Chinese Med, Sch Postgrad, Shenyang 11660, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
3.Inst Proc Engn, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Beijing 100190, Peoples R China
5.Hebei Normal Univ, Coll Chem & Mat, Shijiazhuang 050016, Peoples R China
6.Two Five Eight Hlth Technol Co Ltd, Beijing 100045, Peoples R China
7.Peking Univ, Sch Clin Med 3, Beijing 100083, Peoples R China
8.Ninghai Doubly Adv Mat Co Ltd, Ninghai 315602, Peoples R China
9.Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA
Recommended Citation
GB/T 7714
Gao, Dan-Qing,Li, Xiao-Pei,Shi, Jia-Jia,et al. Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metal ions[J]. CHINESE CHEMICAL LETTERS,2015,26(2):177-181.
APA Gao, Dan-Qing.,Li, Xiao-Pei.,Shi, Jia-Jia.,Kang, Xiao-Yan.,Kang, Ting-Guo.,...&Wu, Jin-Guang.(2015).Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metal ions.CHINESE CHEMICAL LETTERS,26(2),177-181.
MLA Gao, Dan-Qing,et al."Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metal ions".CHINESE CHEMICAL LETTERS 26.2(2015):177-181.
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