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Electrochemical Deposition of Poly[N,N '-ethylene-bis(salicylideneiminato)- nickel(II)] Nanobelts as Electrode Materials for Supercapacitors
Zhang, Yakun1; Li, Jianling1; Wang, Xindong1; Ye, Feng2; Yang, Jun2
2014-02-05
Source PublicationJOURNAL OF APPLIED POLYMER SCIENCE
ISSN0021-8995
Volume131Issue:3Pages:39561
Abstract

N,N-ethylene-bis(salicylideneiminato)]-nickel(II) [Ni(salen)] was synthesized in situ onto the surface of multiwalled carbon nanotubes via a one-step potentiostatic electrodeposition as one-dimensional nanobelts. The synthetic process was free of any templates or additives. Potential played a key role in the formation of the poly[N,N-ethylene-bis(salicylideneiminato)]-nickel(II)] {poly[Ni(salen)]} nanobelts, and the electrical conductivities of the poly[Ni(salen)] decreased with increasing deposition time. The capacitance values of poly[Ni(salen)] were 272, 195, and 146 F/g at 0.05 mA/cm(2) for deposition times of 10, 20, and 30 min, respectively. The capacitance of the sample with a particle structure was much lower than that of poly[Ni(salen)] with a nanobelt structure. The poly[Ni(salen)] nanobelts exhibited a better capacitive behavior than the poly[Ni(salen)] particles because the nanobelt structure made access for the charge and ion to the inner part of the electrode easier. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 39561.

KeywordBatteries And Fuel Cells Conducting Polymers Electrochemistry Nanostructured Polymers
SubtypeArticle
Subject AreaPolymer Science
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1002/app.39561
Indexed BySCI
Language英语
WOS KeywordConducting Polymer ; Films ; Carbon ; Performance ; Salen ; Impedance
Funding ProjectNational Natural Foundation of China [51372021] ; Program for New Century Excellent Talents in University [NCET-09-0215] ; National High Technology Research and Development Program of China (863 Program) [2012AA110302] ; State Key Laboratory of Multiphase Complex Systems [MPCS-2011-D-08]
WOS Research AreaPolymer Science
WOS SubjectPolymer Science
WOS IDWOS:000331300900009
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/15250
Collection研究所(批量导入)
Corresponding AuthorLi, Jianling
Affiliation1.Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Yakun,Li, Jianling,Wang, Xindong,et al. Electrochemical Deposition of Poly[N,N '-ethylene-bis(salicylideneiminato)- nickel(II)] Nanobelts as Electrode Materials for Supercapacitors[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2014,131(3):39561.
APA Zhang, Yakun,Li, Jianling,Wang, Xindong,Ye, Feng,&Yang, Jun.(2014).Electrochemical Deposition of Poly[N,N '-ethylene-bis(salicylideneiminato)- nickel(II)] Nanobelts as Electrode Materials for Supercapacitors.JOURNAL OF APPLIED POLYMER SCIENCE,131(3),39561.
MLA Zhang, Yakun,et al."Electrochemical Deposition of Poly[N,N '-ethylene-bis(salicylideneiminato)- nickel(II)] Nanobelts as Electrode Materials for Supercapacitors".JOURNAL OF APPLIED POLYMER SCIENCE 131.3(2014):39561.
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