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Controllable explosion: fine-tuning the sensitivity of high-energy complexes
Wang, Kun1,2; Zeng, Dihao2; Zhang, Jian-Guo1; Cui, Yan3; Zhang, Tong-Lai1; Li, Zhi-Min4; Jin, Xin2
2015
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Volume44Issue:28Pages:12497-12501
Abstract

Tuning the sensitivity of energetic materials has always been a research topic of interest. A lot of attention has been paid on changing the ligands previously used in traditional high energy density materials (HEDMs). Recently, we have stepped further along this path by thinking from another angle, i.e., changing the metal centre. Herein, we report 4 transition metal complexes bearing the 1,5-diaminotetrazole ligand, which have similar structures but drastically different sensitivities. These differences are apparently due to the different metal centres used.

SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c5dt01462j
Indexed BySCI
Language英语
WOS KeywordPOTENTIAL BASIS-SETS ; POLARIZATION FUNCTIONS ; CRYSTAL-STRUCTURE ; IONIC LIQUIDS ; 1,5-DIAMINOTETRAZOLE ; COMPOUND ; DENSITY ; SALTS ; DERIVATIVES ; THERMOCHEMISTRY
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000357899600006
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/19396
Collection多相复杂系统国家重点实验室
Affiliation1.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
2.Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QR, England
3.Res Inst Chem Def, Dept 6, Beijing 102205, Peoples R China
4.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Kun,Zeng, Dihao,Zhang, Jian-Guo,et al. Controllable explosion: fine-tuning the sensitivity of high-energy complexes[J]. DALTON TRANSACTIONS,2015,44(28):12497-12501.
APA Wang, Kun.,Zeng, Dihao.,Zhang, Jian-Guo.,Cui, Yan.,Zhang, Tong-Lai.,...&Jin, Xin.(2015).Controllable explosion: fine-tuning the sensitivity of high-energy complexes.DALTON TRANSACTIONS,44(28),12497-12501.
MLA Wang, Kun,et al."Controllable explosion: fine-tuning the sensitivity of high-energy complexes".DALTON TRANSACTIONS 44.28(2015):12497-12501.
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