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A heterometallic nanosized tube {Fe[(CN)(6)](2)[Co(LN3O2)](3)}(n) and two of its lamellar polymorphous isomers
Pan, F.1,2; Gao, S.1; Liu, H. Z.2
2015
Source PublicationCRYSTENGCOMM
ISSN1466-8033
Volume17Issue:39Pages:7490-7495
AbstractSingle crystals of three polymorphous compounds were synthesized started from two building blocks, [Fe(CN)(6)](3-) and [Co(L-N3O2)](2+) (L is a Schiff-base macrocyclic ligand derived from the condensation of 2,6-diacetylpyridine with 3,6-dioxaoctane-1,8-diamine) using a crystallization condition control. All three compounds consist of electroneutral skeletons made up of Fe6Co6 twelve-metal ring units, which is the smallest enclosed circle in their structures: 1 is comprised of 1D nanometer-diameter tubes possessing nanometer-sized tunnels (0.58 nm x 0.74 nm); 2 and 3 are based on piled-up 2D lamellar layers in the (6, 3) and (4, 4) networks, respectively. Magnetic studies indicate ferromagnetic interactions between cyanide-bridged cobalt(II) and iron(III) in each compound.
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c5ce01185j
Indexed BySCI
Language英语
WOS KeywordSLOW MAGNETIC-RELAXATION ; COMPLEXES ; MACROCYCLE ; IRON(II) ; CRYSTAL ; RECOGNITION ; NANOTUBES ; COMPOUND ; BEHAVIOR ; LIGANDS
WOS Research AreaChemistry ; Crystallography
WOS SubjectChemistry, Multidisciplinary ; Crystallography
WOS IDWOS:000362351900008
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/19612
Collection生化工程国家重点实验室
Affiliation1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Pan, F.,Gao, S.,Liu, H. Z.. A heterometallic nanosized tube {Fe[(CN)(6)](2)[Co(LN3O2)](3)}(n) and two of its lamellar polymorphous isomers[J]. CRYSTENGCOMM,2015,17(39):7490-7495.
APA Pan, F.,Gao, S.,&Liu, H. Z..(2015).A heterometallic nanosized tube {Fe[(CN)(6)](2)[Co(LN3O2)](3)}(n) and two of its lamellar polymorphous isomers.CRYSTENGCOMM,17(39),7490-7495.
MLA Pan, F.,et al."A heterometallic nanosized tube {Fe[(CN)(6)](2)[Co(LN3O2)](3)}(n) and two of its lamellar polymorphous isomers".CRYSTENGCOMM 17.39(2015):7490-7495.
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