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Study on palm oil hydrogenation for clean fuel over Ni-Mo-W/gamma-Al2O3-ZSM-5 catalyst | |
Wang, Hong-Yan1,2; Jiao, Tian-Tian2; Li, Zeng-Xi1; Li, Chun-Shan2; Zhang, Suo-Jiang2; Zhang, Jian-Ling3 | |
2015-11-01 | |
Source Publication | FUEL PROCESSING TECHNOLOGY
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ISSN | 0378-3820 |
Volume | 139Issue:NOVPages:91-99 |
Abstract | Biodiesel, derived from vegetable oil via hydrotreating, is becoming a promising alternative energy. Novel Ni-Mo-W/gamma-Al2O3-ZSM-5 catalysts were developed and firstly applied in palm oil hydrogenation process. The catalysts were prepared by extrusion method and characterized by XRD, SEM, TEM, BET, NH3-TPD, and H-2-TPR The influences of acidity on the activity, selectivity, and stability of catalysts were systematically studied. The mechanisms of deoxygenation and isomerization were discussed. The catalyst Ni-Mo-W (5 wt.%-5 wt.%-15 wt.%)/gamma-Al2O3-ZSM-5 (85 wt.% 15 wt.%) was confirmed as the optimum one. Finally, the key reaction parameters such as reaction temperature, pressure, liquid hourly space velocity and H-2/oil volume ratio were optimized. The hydrogenation reaction path of palm oil was also proposed. (C) 2015 Elsevier B.V. All rights reserved. |
Keyword | Hydrogenation Palm Oil Biodiesel Cetane Number |
Subtype | Article |
WOS Headings | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/j.fuproc.2015.08.004 |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | SUPPORTED NICKEL-CATALYSTS ; BIODIESEL PRODUCTION ; VEGETABLE-OILS ; JATROPHA OIL ; SOYBEAN OIL ; COAL-TAR ; HYDRODEOXYGENATION ; DEOXYGENATION ; TRIGLYCERIDES ; DIESEL |
WOS Research Area | Chemistry ; Energy & Fuels ; Engineering |
WOS Subject | Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical |
WOS ID | WOS:000362619200012 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/19614 |
Collection | 研究所(批量导入) |
Affiliation | 1.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
Recommended Citation GB/T 7714 | Wang, Hong-Yan,Jiao, Tian-Tian,Li, Zeng-Xi,et al. Study on palm oil hydrogenation for clean fuel over Ni-Mo-W/gamma-Al2O3-ZSM-5 catalyst[J]. FUEL PROCESSING TECHNOLOGY,2015,139(NOV):91-99. |
APA | Wang, Hong-Yan,Jiao, Tian-Tian,Li, Zeng-Xi,Li, Chun-Shan,Zhang, Suo-Jiang,&Zhang, Jian-Ling.(2015).Study on palm oil hydrogenation for clean fuel over Ni-Mo-W/gamma-Al2O3-ZSM-5 catalyst.FUEL PROCESSING TECHNOLOGY,139(NOV),91-99. |
MLA | Wang, Hong-Yan,et al."Study on palm oil hydrogenation for clean fuel over Ni-Mo-W/gamma-Al2O3-ZSM-5 catalyst".FUEL PROCESSING TECHNOLOGY 139.NOV(2015):91-99. |
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Study on palm oil hy(1785KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text |
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