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Ti-2-Containing 18-Tungsto-2-Arsenate(III) Monolacunary Host and the Incorporation of a Phenylantimony(III) Guest
Wang, Kai-Yao1; Lin, Zhengguo1; Bassil, Bassem. S.1,2; Xing, Xiaolin1; Haider, Ali1; Keita, Bineta3; Zhang, Guangjin4; Silvestru, Cristian5; Kortz, Ulrich1
2015-11-16
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume54Issue:22Pages:10530-10532
AbstractThe novel Ti-2-containing, sandwich-type 18-tungsto-2-arsenate(III) [ ((TiO)-O-IV)(2) (alpha-(AsW9O33)-W-III)(2)](14-) (1) was successfully synthesized by the reaction of [TiO](2+) species with [alpha-(AsW9O33)-W-III](9-). The monolacunary polyanion 1 is solution-stable, and a further reaction with 1 equiv of phenylantimony(III) dichloride resulted in [C6H5SbIII((TiO)-O-IV)(2)(alpha-(AsW9O33)-W-III)(2)](12-) (2). Both polyanions 1 and 2 were structurally characterized in the solid state and solution. Electrochemical studies were also performed on both polyanions.
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1021/acs.inorgchem.5b01863
Indexed BySCI
Language英语
WOS KeywordSTRUCTURAL CHARACTERIZATION ; X-RAY ; HETEROPOLYANION ; HETEROPOLYTUNGSTATES ; POLYOXOTUNGSTATE ; COMPLEXES ; CATIONS ; CE
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
Funding OrganizationGerman Research Council(DFG KO-2288/20-1) ; Jacobs University ; Chinese Academy of Sciences President's International Fellowship Initiative(2015VMA041) ; CMST COST Action(CM1203) ; China Scholarship Council ; National Natural Science Foundation of China(21371173) ; National Research Council of Romania(PN-II-ID-PCE-2011-3-0933)
WOS IDWOS:000364981300004
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/19901
Collection湿法冶金清洁生产技术国家工程实验室
Affiliation1.Jacobs Univ Bremen, Dept Life Sci & Chem, D-28725 Bremen, Germany
2.Univ Balamand, Dept Chem, Fac Sci, Tripoli, Libya
3.Univ Paris 11, Chim Phys Lab, UMR CNRS 8000, F-91405 Orsay, France
4.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
5.Univ Babes Bolyai, Dept Chem, Supramol Organ & Organometall Chem Ctr, Fac Chem & Chem Engn, RO-400028 Cluj Napoca, Romania
Recommended Citation
GB/T 7714
Wang, Kai-Yao,Lin, Zhengguo,Bassil, Bassem. S.,et al. Ti-2-Containing 18-Tungsto-2-Arsenate(III) Monolacunary Host and the Incorporation of a Phenylantimony(III) Guest[J]. INORGANIC CHEMISTRY,2015,54(22):10530-10532.
APA Wang, Kai-Yao.,Lin, Zhengguo.,Bassil, Bassem. S..,Xing, Xiaolin.,Haider, Ali.,...&Kortz, Ulrich.(2015).Ti-2-Containing 18-Tungsto-2-Arsenate(III) Monolacunary Host and the Incorporation of a Phenylantimony(III) Guest.INORGANIC CHEMISTRY,54(22),10530-10532.
MLA Wang, Kai-Yao,et al."Ti-2-Containing 18-Tungsto-2-Arsenate(III) Monolacunary Host and the Incorporation of a Phenylantimony(III) Guest".INORGANIC CHEMISTRY 54.22(2015):10530-10532.
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