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Oxidation behavior of metallurgical silicon slag under non-isothermal and isothermal conditions
Cao, Jianwei1; Lu, Jinshan2; Jiang, Longxiang2; Wang, Zhi1
2016-05-01
发表期刊JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN1388-6150
卷号124期号:2页码:593-599
摘要Metallurgical silicon slag is the by-product of metallic silicon industry. The utilization of silicon slag is very limited due to the absence of related researches. In this work, the oxidation behavior of metallurgical silicon slag was studied by means of phase variation under the non-isothermal and isothermal conditions. The crystal structure and phase composition of silicon slags were investigated by X-ray powder diffraction, simultaneous thermal analysis, scanning electron microscopy and thermogravimetry. During the oxidation process, the CO2 emission was progressively enhanced with increasing the oxidation temperature, and the exothermic oxidation primarily occurred above 700 A degrees C. The non-isothermal oxidation of silicon slag powder was a complicated process, involving the oxidation, crystal precipitation and disproportionation processes. The graphite phase was completely removed at 1000 A degrees C. The SiC and cristobalite phases greatly increased at 750 A degrees C and decreased with further increasing the oxidation temperature. For the isothermal oxidation, the Si and SiC phases generally reduced with increasing the soaking time. The cristobalite and tridymite phases increased with the oxidation time. The mass change in slag powders suggested that the isothermal oxidation process consisted of the initial redox reaction and subsequent oxidation reaction.
关键词Metallurgical Silicon Slag Oxidation Behavior Phase Composition Microstructure Thermogravimetry
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1007/s10973-015-5157-0
收录类别SCI
语种英语
关键词[WOS]PARTICLE-SIZE ; COPPER SLAG ; CARBIDE ; GLASS ; CRYSTALLIZATION ; REDUCTION ; KINETICS ; POWDERS ; METALS
WOS研究方向Thermodynamics ; Chemistry
WOS类目Thermodynamics ; Chemistry, Analytical ; Chemistry, Physical
项目资助者National Natural Science Foundation of China(51404225 ; 51422405)
WOS记录号WOS:000373576600003
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/20089
专题研究所(批量导入)
作者单位1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
2.Nanchang Hangkong Univ, Sch Mat Sci & Engn, Nanchang 3330063, Peoples R China
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Cao, Jianwei,Lu, Jinshan,Jiang, Longxiang,et al. Oxidation behavior of metallurgical silicon slag under non-isothermal and isothermal conditions[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2016,124(2):593-599.
APA Cao, Jianwei,Lu, Jinshan,Jiang, Longxiang,&Wang, Zhi.(2016).Oxidation behavior of metallurgical silicon slag under non-isothermal and isothermal conditions.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,124(2),593-599.
MLA Cao, Jianwei,et al."Oxidation behavior of metallurgical silicon slag under non-isothermal and isothermal conditions".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 124.2(2016):593-599.
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