CAS OpenIR  > 多相复杂系统国家重点实验室
Catalytic Depolymerization of Organosolv Lignin in a Novel Water/Oil Emulsion Reactor: Lignin as the Self-Surfactant
Cai, Zhenping1; Li, Yingwen1; He, Hongyan2; Zeng, Qiang1; Long, Jinxing1; Wang, Lefu1; Li, Xuehui1
2015-11-25
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume54Issue:46Pages:11501-11510
AbstractA novel and efficient water/oil emulsion reactor for organosolv lignin depolymerization is presented using an ionic liquid catalyst based on the self-surfactivity of lignin. The physicalchemical properties of the emulsion reactor and lignin were intensively studied using optical photo, dynamic light scattering, surface tension measurement, and hydrophilelipophile balance value determination. The results show that the emulsion reactor demonstrates a more significant process intensification effect on lignin depolymerization, with more than 29.60 mg g(-1) desired phenolic compounds obtained, which is about 3.3 times higher than that from a reactor without emulsification. Another advantage of this water/oil emulsion reactor is that both the organic solvent (n-butanol) and the ionic liquid catalyst can be recycled easily, as the depletion of lignin surfactant at the end of depolymerization can result in the phase partition and the enrichment of final products in the oil phase automatically.
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1021/acs.iecr.5b03247
Indexed BySCI
Language英语
WOS KeywordACIDIC IONIC LIQUIDS ; EFFICIENT CATALYST ; HYDROGENOLYSIS ; CHEMICALS ; BAGASSE ; SYSTEM ; DECOMPOSITION ; LIQUEFACTION ; STABILITY
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNatural Science Foundation of China(21336002 ; Natural Science Foundation of Guangdong Province, China(2015A030311048) ; 21276094 ; 51306191 ; 21406230)
WOS IDWOS:000366005200001
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/20147
Collection多相复杂系统国家重点实验室
Affiliation1.S China Univ Technol, Pulp & Paper Engn State Key Lab China, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Cai, Zhenping,Li, Yingwen,He, Hongyan,et al. Catalytic Depolymerization of Organosolv Lignin in a Novel Water/Oil Emulsion Reactor: Lignin as the Self-Surfactant[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2015,54(46):11501-11510.
APA Cai, Zhenping.,Li, Yingwen.,He, Hongyan.,Zeng, Qiang.,Long, Jinxing.,...&Li, Xuehui.(2015).Catalytic Depolymerization of Organosolv Lignin in a Novel Water/Oil Emulsion Reactor: Lignin as the Self-Surfactant.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,54(46),11501-11510.
MLA Cai, Zhenping,et al."Catalytic Depolymerization of Organosolv Lignin in a Novel Water/Oil Emulsion Reactor: Lignin as the Self-Surfactant".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 54.46(2015):11501-11510.
Files in This Item:
File Name/Size DocType Version Access License
Catalytic Depolymeri(6850KB)期刊论文出版稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Cai, Zhenping]'s Articles
[Li, Yingwen]'s Articles
[He, Hongyan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Cai, Zhenping]'s Articles
[Li, Yingwen]'s Articles
[He, Hongyan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Cai, Zhenping]'s Articles
[Li, Yingwen]'s Articles
[He, Hongyan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.