| Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids | |
| Fei, Teng; Cai, Huiwu; Zhang, Yanqiang2; Liu, Long; Zhang, Suojiang | |
| 2016-04-02 | |
| 发表期刊 | JOURNAL OF ENERGETIC MATERIALS
 |
| ISSN | 0737-0652 |
| 卷号 | 34期号:2页码:138-151 |
| 摘要 | Four energetic salts (including two ionic liquids) based on 2-(dimethylamino)-N,N,N-trimethylethanaminium and N,N-dialkyl-N,N,N,N-tetramethylethane-1,2-diaminium was prepared and characterized by H-1- and C-13-NMR, infrared and Raman spectroscopies, and elemental analysis. Their physicochemical properties such as melting and decomposition temperatures, density, viscosity, heat of formation, detonation performance, and specific impulse were measured or calculated. With thermal stability up to 200 degrees C, the resulting ionic liquids show densities from 1.02 to 1.19 g cm(-3) and heats of formation from 85.1 to 154.4 kJ mol(-1). Moreover, 2-(dimethylamino)-N,N,N-trimethylethanaminium dicyanamide is hypergolic with the oxidizer (100% HNO3) and exhibits potential as a green fuel for bipropellants. |
| 关键词 | Dicyanamide Heat Of Formation Hypergolic Specific Impulse Tetramethylethylenediamine |
| 文章类型 | Article |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1080/07370652.2015.1017669 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | ENERGETIC SALTS ; FLUIDS ; CATION ; FUELS |
| WOS研究方向 | Chemistry ; Engineering ; Materials Science |
| WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical ; Materials Science, Multidisciplinary |
| 项目资助者 | National Natural Science Foundation of China(21376252 ; National Defense Science and Technology Innovation Fund of Chinese Academy of Sciences(CXJJ-14-M37 ; 21406242) ; CXJJ-14-M41) |
| WOS记录号 | WOS:000367067200004 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.ipe.ac.cn/handle/122111/20190 |
| 专题 | 多相复杂系统国家重点实验室 |
| 作者单位 | 1.Xian Univ Sci & Technol, Sch Chem & Chem Engn, Xian, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fei, Teng,Cai, Huiwu,Zhang, Yanqiang,et al. Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids[J]. JOURNAL OF ENERGETIC MATERIALS,2016,34(2):138-151. |
| APA | Fei, Teng,Cai, Huiwu,Zhang, Yanqiang,Liu, Long,&Zhang, Suojiang.(2016).Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids.JOURNAL OF ENERGETIC MATERIALS,34(2),138-151. |
| MLA | Fei, Teng,et al."Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids".JOURNAL OF ENERGETIC MATERIALS 34.2(2016):138-151. |
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| Synthesis and Charac（1283KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 浏览 请求全文 | |
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