| Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids | |
| Fei, Teng; Cai, Huiwu; Zhang, Yanqiang2; Liu, Long; Zhang, Suojiang | |
| 2016-04-02 | |
| Source Publication | JOURNAL OF ENERGETIC MATERIALS
 |
| ISSN | 0737-0652 |
| Volume | 34Issue:2Pages:138-151 |
| Abstract | Four energetic salts (including two ionic liquids) based on 2-(dimethylamino)-N,N,N-trimethylethanaminium and N,N-dialkyl-N,N,N,N-tetramethylethane-1,2-diaminium was prepared and characterized by H-1- and C-13-NMR, infrared and Raman spectroscopies, and elemental analysis. Their physicochemical properties such as melting and decomposition temperatures, density, viscosity, heat of formation, detonation performance, and specific impulse were measured or calculated. With thermal stability up to 200 degrees C, the resulting ionic liquids show densities from 1.02 to 1.19 g cm(-3) and heats of formation from 85.1 to 154.4 kJ mol(-1). Moreover, 2-(dimethylamino)-N,N,N-trimethylethanaminium dicyanamide is hypergolic with the oxidizer (100% HNO3) and exhibits potential as a green fuel for bipropellants. |
| Keyword | Dicyanamide Heat Of Formation Hypergolic Specific Impulse Tetramethylethylenediamine |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1080/07370652.2015.1017669 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | ENERGETIC SALTS ; FLUIDS ; CATION ; FUELS |
| WOS Research Area | Chemistry ; Engineering ; Materials Science |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical ; Materials Science, Multidisciplinary |
| Funding Organization | National Natural Science Foundation of China(21376252 ; National Defense Science and Technology Innovation Fund of Chinese Academy of Sciences(CXJJ-14-M37 ; 21406242) ; CXJJ-14-M41) |
| WOS ID | WOS:000367067200004 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/20190 |
| Collection | 多相复杂系统国家重点实验室 |
| Affiliation | 1.Xian Univ Sci & Technol, Sch Chem & Chem Engn, Xian, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Fei, Teng,Cai, Huiwu,Zhang, Yanqiang,et al. Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids[J]. JOURNAL OF ENERGETIC MATERIALS,2016,34(2):138-151. |
| APA | Fei, Teng,Cai, Huiwu,Zhang, Yanqiang,Liu, Long,&Zhang, Suojiang.(2016).Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids.JOURNAL OF ENERGETIC MATERIALS,34(2),138-151. |
| MLA | Fei, Teng,et al."Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids".JOURNAL OF ENERGETIC MATERIALS 34.2(2016):138-151. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Synthesis and Charac（1283KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text | |
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