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Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids
Fei, Teng; Cai, Huiwu; Zhang, Yanqiang2; Liu, Long; Zhang, Suojiang
2016-04-02
Source PublicationJOURNAL OF ENERGETIC MATERIALS
ISSN0737-0652
Volume34Issue:2Pages:138-151
AbstractFour energetic salts (including two ionic liquids) based on 2-(dimethylamino)-N,N,N-trimethylethanaminium and N,N-dialkyl-N,N,N,N-tetramethylethane-1,2-diaminium was prepared and characterized by H-1- and C-13-NMR, infrared and Raman spectroscopies, and elemental analysis. Their physicochemical properties such as melting and decomposition temperatures, density, viscosity, heat of formation, detonation performance, and specific impulse were measured or calculated. With thermal stability up to 200 degrees C, the resulting ionic liquids show densities from 1.02 to 1.19 g cm(-3) and heats of formation from 85.1 to 154.4 kJ mol(-1). Moreover, 2-(dimethylamino)-N,N,N-trimethylethanaminium dicyanamide is hypergolic with the oxidizer (100% HNO3) and exhibits potential as a green fuel for bipropellants.
KeywordDicyanamide Heat Of Formation Hypergolic Specific Impulse Tetramethylethylenediamine
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1080/07370652.2015.1017669
Indexed BySCI
Language英语
WOS KeywordENERGETIC SALTS ; FLUIDS ; CATION ; FUELS
WOS Research AreaChemistry ; Engineering ; Materials Science
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical ; Materials Science, Multidisciplinary
Funding OrganizationNational Natural Science Foundation of China(21376252 ; National Defense Science and Technology Innovation Fund of Chinese Academy of Sciences(CXJJ-14-M37 ; 21406242) ; CXJJ-14-M41)
WOS IDWOS:000367067200004
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/20190
Collection多相复杂系统国家重点实验室
Affiliation1.Xian Univ Sci & Technol, Sch Chem & Chem Engn, Xian, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Fei, Teng,Cai, Huiwu,Zhang, Yanqiang,et al. Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids[J]. JOURNAL OF ENERGETIC MATERIALS,2016,34(2):138-151.
APA Fei, Teng,Cai, Huiwu,Zhang, Yanqiang,Liu, Long,&Zhang, Suojiang.(2016).Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids.JOURNAL OF ENERGETIC MATERIALS,34(2),138-151.
MLA Fei, Teng,et al."Synthesis and Characterization of Tetramethylethylenediamine-Based Hypergolic Ionic Liquids".JOURNAL OF ENERGETIC MATERIALS 34.2(2016):138-151.
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