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Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions
Guo, Ya-Fei; Xu, Bao-Hua; Li, Ting; Wang, Lei; Zhang, Suo-Jiang
2016
Source PublicationORGANIC CHEMISTRY FRONTIERS
ISSN2052-4129
Volume3Issue:1Pages:47-52
AbstractThe efficient cobalt(II) catalyzed oxidative alkoxylation of aldehydes, a method directly leading to the corresponding esters, is presented. Mechanism studies provide extensive insights into the cobalt mediated decomposition of TBHP in the presence of the iodide ion. The in situ generated hypoiodites (IO-/IO2-) mainly from conversion of I-3(-) to IO3- account for a cooperative effect with the oxygen centered radical species to make the important hydrogen abstraction of hemiacetal intermediates more selective, thereby offering high efficiency.
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1039/c5qo00293a
Indexed BySCI
Language英语
WOS KeywordCATALYZED DIRECT ARYLATION ; CROSS-COUPLING REACTIONS ; C-H BOND ; TRANSITION-METALS ; AEROBIC OXIDATION ; AROMATIC IMINES ; CARBON-HYDROGEN ; BENZYL ALCOHOLS ; AMIDATION ; AMINES
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
Funding OrganizationNational Key Basic Research Program of China (973 Program)(2015CB251401) ; National Natural Science Foundation of China(21476240 ; CAS 100-Talent Program ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDA07070600) ; 21127011)
WOS IDWOS:000366864700007
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/20196
Collection多相复杂系统国家重点实验室
AffiliationChinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Guo, Ya-Fei,Xu, Bao-Hua,Li, Ting,et al. Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(1):47-52.
APA Guo, Ya-Fei,Xu, Bao-Hua,Li, Ting,Wang, Lei,&Zhang, Suo-Jiang.(2016).Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions.ORGANIC CHEMISTRY FRONTIERS,3(1),47-52.
MLA Guo, Ya-Fei,et al."Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions".ORGANIC CHEMISTRY FRONTIERS 3.1(2016):47-52.
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