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Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions
Guo, Ya-Fei; Xu, Bao-Hua; Li, Ting; Wang, Lei; Zhang, Suo-Jiang
2016
发表期刊ORGANIC CHEMISTRY FRONTIERS
ISSN2052-4129
卷号3期号:1页码:47-52
摘要The efficient cobalt(II) catalyzed oxidative alkoxylation of aldehydes, a method directly leading to the corresponding esters, is presented. Mechanism studies provide extensive insights into the cobalt mediated decomposition of TBHP in the presence of the iodide ion. The in situ generated hypoiodites (IO-/IO2-) mainly from conversion of I-3(-) to IO3- account for a cooperative effect with the oxygen centered radical species to make the important hydrogen abstraction of hemiacetal intermediates more selective, thereby offering high efficiency.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c5qo00293a
收录类别SCI
语种英语
关键词[WOS]CATALYZED DIRECT ARYLATION ; CROSS-COUPLING REACTIONS ; C-H BOND ; TRANSITION-METALS ; AEROBIC OXIDATION ; AROMATIC IMINES ; CARBON-HYDROGEN ; BENZYL ALCOHOLS ; AMIDATION ; AMINES
WOS研究方向Chemistry
WOS类目Chemistry, Organic
项目资助者National Key Basic Research Program of China (973 Program)(2015CB251401) ; National Natural Science Foundation of China(21476240 ; CAS 100-Talent Program ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDA07070600) ; 21127011)
WOS记录号WOS:000366864700007
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/20196
专题多相复杂系统国家重点实验室
作者单位Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
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GB/T 7714
Guo, Ya-Fei,Xu, Bao-Hua,Li, Ting,et al. Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(1):47-52.
APA Guo, Ya-Fei,Xu, Bao-Hua,Li, Ting,Wang, Lei,&Zhang, Suo-Jiang.(2016).Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions.ORGANIC CHEMISTRY FRONTIERS,3(1),47-52.
MLA Guo, Ya-Fei,et al."Cobalt(II)-catalyzed oxidative esterification of aldehydes: a cooperative effect between cobalt and iodide ions".ORGANIC CHEMISTRY FRONTIERS 3.1(2016):47-52.
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