Solubility investigations in the NaOH-Na3VO4-Na2CrO4-Na2CO3- H2O system at (40 and 80) degrees C
Feng, Man1,2; Wang, Shaona1; Du, Hao1; Zheng, Shili1; Zhang, Yi1
2016-02-15
发表期刊FLUID PHASE EQUILIBRIA
ISSN0378-3812
卷号409期号:FEB页码:119-123
摘要To realize the effective separation of Na3VO4, Na2CrO4 and the impurity Na2CO3 in a newly developed vanadium production process using concentrated alkaline solution as reaction media, the equilibrium liquid phase solubility and solid phase compositions of the NaOH-Na3VO4-Na2CrO4-Na2CO3-H2O system at (40 and 80) degrees C were measured. The obtained solubility data were afterwards compared with quaternary NaOH-Na3VO4-Na2CrO4-H2O subsystem to investigate the salting-out effect of Na3VO4, Na2CrO4 and Na2CO3. Further, a strategy for effective separation of Na3VO4 and Na2CrO4 from the NaOH Na3VO4-Na2CrO4-Na2CO3-H2O pentabasic system has been proposed on the basis of detailed analysis of crystallization zones. (c) 2015 Published by Elsevier B.V.
关键词Na3vo4 Na2cro4 Na2co3 Crystallization Solubility
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.fluid.2015.08.018
收录类别SCI
语种英语
关键词[WOS]VANADIUM SLAG ; EXTRACTION ; OXIDATION ; KINETICS ; LIQUID
WOS研究方向Thermodynamics ; Chemistry ; Engineering
WOS类目Thermodynamics ; Chemistry, Physical ; Engineering, Chemical
项目资助者Major State Basic Research Development Program of China (973 program)(2013CB632605 ; National Natural Science Foundation of China(51274179) ; 2013CB632601)
WOS记录号WOS:000367860400016
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/20257
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Natl Engn Lab Hydrometall Cleaner Prod Technol, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Feng, Man,Wang, Shaona,Du, Hao,et al. Solubility investigations in the NaOH-Na3VO4-Na2CrO4-Na2CO3- H2O system at (40 and 80) degrees C[J]. FLUID PHASE EQUILIBRIA,2016,409(FEB):119-123.
APA Feng, Man,Wang, Shaona,Du, Hao,Zheng, Shili,&Zhang, Yi.(2016).Solubility investigations in the NaOH-Na3VO4-Na2CrO4-Na2CO3- H2O system at (40 and 80) degrees C.FLUID PHASE EQUILIBRIA,409(FEB),119-123.
MLA Feng, Man,et al."Solubility investigations in the NaOH-Na3VO4-Na2CrO4-Na2CO3- H2O system at (40 and 80) degrees C".FLUID PHASE EQUILIBRIA 409.FEB(2016):119-123.
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