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Thermodynamics and Separation Process for Quaternary Acrylic Systems
Zuo, Cuncun; Li, Yaping; Li, Chunshan; Cao, Shasha; Yao, Haoyu; Zhang, Suojiang
2016
发表期刊AICHE JOURNAL
ISSN0001-1541
卷号62期号:1页码:228-240
摘要Vapor-liquid equilibrium (VLE) and liquid-liquid equilibrium (LLE) data of binary and ternary acrylic systems were systematically measured. Subsequently, VLLE phase diagrams of binary systems, tridimensional VLE phase diagrams of methyl acrylate (MA)-methanol (Me)-H2O ternary system, and quaternary LLE phase diagrams of MA-Me-H2O-methyl acetate (MeOAc) system were constructed. These diagrams clearly demonstrated the effects of temperature on phase equilibrium. The experimental data was fitted by the NRTL and UNIQUAC models, and the best-fitted parameters were used to predict interaction properties of ternary and quaternary mixture. Therefore, the phase equilibrium data were provided as reference for the design of acrylic systems rectification or extraction process. Residue curve was mapped out for MA-Me-H2O system through Aspen plus software. Finally, using thermodynamics and residue curve as theoretical basis, two novel separation processes were proposed and applied to the quaternary acrylic systems. (C) 2015 American Institute of Chemical Engineers
关键词Methyl Acrylate Tridimensional Vle Phase Diagrams Quaternary Lle Phase Diagrams Thermodynamics Separation
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1002/aic.15015
收录类别SCI
语种英语
关键词[WOS]VAPOR-LIQUID-EQUILIBRIA ; ACETATE PLUS METHANOL ; METHYL ACETATE ; ACETIC-ACID ; INTERACTION PARAMETERS ; AZEOTROPIC MIXTURES ; PHASE-EQUILIBRIA ; IONIC LIQUIDS ; WATER ; DISTILLATION
WOS研究方向Engineering
WOS类目Engineering, Chemical
项目资助者National Program on Key Basic Research Project(2015CB251401) ; National Natural Science Funds for Distinguished Young Scholar(21425625) ; National Science Fund for Excellent Young Scholars(21422607)
WOS记录号WOS:000367924600018
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/20269
专题多相复杂系统国家重点实验室
作者单位Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China
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Zuo, Cuncun,Li, Yaping,Li, Chunshan,et al. Thermodynamics and Separation Process for Quaternary Acrylic Systems[J]. AICHE JOURNAL,2016,62(1):228-240.
APA Zuo, Cuncun,Li, Yaping,Li, Chunshan,Cao, Shasha,Yao, Haoyu,&Zhang, Suojiang.(2016).Thermodynamics and Separation Process for Quaternary Acrylic Systems.AICHE JOURNAL,62(1),228-240.
MLA Zuo, Cuncun,et al."Thermodynamics and Separation Process for Quaternary Acrylic Systems".AICHE JOURNAL 62.1(2016):228-240.
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