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The Conversion from Magnesium Hydroxychloride to Anhydrous Magnesium Chloride by Solid-State Reaction
Zhang, Zhimin1; Lu, Xuchen3,4; Chen, Shiwei1,2; Wang, Tizhuang1; Yan, Yan1
2016-02-01
发表期刊METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE
ISSN1073-5615
卷号47期号:1页码:773-778
摘要To reduce the content of MgOHCl in anhydrous MgCl2, MgOHCl was converted to anhydrous MgCl2 by solid-state reaction. Factors that affect the conversion effects were investigated, including the mol ratio of NH4Cl to MgOHCl, thickness of covering agent, reaction temperature, and reaction time. The conversion process was characterized by XRD analysis and chemical analysis. The solid-state reaction mechanism was studied and discussed. The MgO content in anhydrous MgCl2 achieved 0.05 pct under the optimal conditions: the mol ratio of NH4Cl to MgOHCl was 3:1, thickness of Al2O3 powder 2 cm, reaction temperature 623 K (350 A degrees C), and reaction time 1 hour.
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1007/s11663-015-0503-y
收录类别SCI
语种英语
关键词[WOS]THERMAL-DECOMPOSITION ; HEXAHYDRATE ; KINETICS
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
项目资助者National Natural Science Foundation of China(U1407136 ; 21406247)
WOS记录号WOS:000368692300070
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文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/20596
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Wuhai 016000, Peoples R China
4.United Res Ctr Resource & Mat, Wuhai 016000, Peoples R China
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GB/T 7714
Zhang, Zhimin,Lu, Xuchen,Chen, Shiwei,et al. The Conversion from Magnesium Hydroxychloride to Anhydrous Magnesium Chloride by Solid-State Reaction[J]. METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE,2016,47(1):773-778.
APA Zhang, Zhimin,Lu, Xuchen,Chen, Shiwei,Wang, Tizhuang,&Yan, Yan.(2016).The Conversion from Magnesium Hydroxychloride to Anhydrous Magnesium Chloride by Solid-State Reaction.METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE,47(1),773-778.
MLA Zhang, Zhimin,et al."The Conversion from Magnesium Hydroxychloride to Anhydrous Magnesium Chloride by Solid-State Reaction".METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE 47.1(2016):773-778.
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