One-step electrochemical preparation of metallic vanadium from sodium metavanadate in molten chlorides
Weng, Wei1; Wang, Mingyong2; Gong, Xuzhong2; Wang, Zhi2; Wang, Dong2; Guo, Zhancheng1
2016-02-01
发表期刊INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS
ISSN0263-4368
卷号55期号:FEB页码:47-53
摘要Conventionally, metallic vanadium is produced from vanadium pentoxide (V2O5). Sodium metavanadate (NaVO3) is an essential intermediate product for the V2O5 production. A novel environmentally friendly route for the metallic vanadium preparation from NaVO3 by molten salt electrolysis is proposed. In the NaCl molten salt, NaVO3 has a high solubility of 8.6 mol% (163 wt.%) at 1173 K and was easily electro-reduced to V2O3. However, V2O3 is almost insoluble in the NaCl molten salt, and thus can't be further electro-reduced to metallic vanadium. In the eutectic CaCl2-NaCl molten salt, NaVO3 was converted to CaV2O6. CaV2O4 as the intermediate product was produced during CaV2O6 electrolysis and can be dissolved into the eutectic CaCl2-NaCl molten salt. The dissolved CaV2O4 was further electro-reduced to metallic vanadium. (C) 2015 Elsevier Ltd. All rights reserved.
关键词Molten Salt Electrolysis Metallic Vanadium Electrochemical Reduction Sodium Metavanadate
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1016/j.ijrmhm.2015.11.007
收录类别SCI
语种英语
关键词[WOS]ELECTRO-DEOXIDATION ; TUNGSTEN POWDER ; REDUCTION ; SALT ; TITANIUM ; SYSTEM ; CACL2 ; OXIDE ; NACL ; KCL
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
项目资助者National Basic Research Program of China (973)(2013CB632606) ; National Natural Science Foundation of China(51474200) ; Youth Innovation Promotion Association, CAS(2015036)
WOS记录号WOS:000369201900007
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/20605
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China
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Weng, Wei,Wang, Mingyong,Gong, Xuzhong,et al. One-step electrochemical preparation of metallic vanadium from sodium metavanadate in molten chlorides[J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS,2016,55(FEB):47-53.
APA Weng, Wei,Wang, Mingyong,Gong, Xuzhong,Wang, Zhi,Wang, Dong,&Guo, Zhancheng.(2016).One-step electrochemical preparation of metallic vanadium from sodium metavanadate in molten chlorides.INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS,55(FEB),47-53.
MLA Weng, Wei,et al."One-step electrochemical preparation of metallic vanadium from sodium metavanadate in molten chlorides".INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS 55.FEB(2016):47-53.
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