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Hydrogen-bonding interactions between a pyridinium-based ionic liquid [C4Py][SCN] and dimethyl sulfoxide
He, HY; Chen, H; Zheng, YZ; Zhang, SJ; Yu, ZW
2015
Source PublicationCHEMICAL ENGINEERING SCIENCE
ISSN0009-2509
Volume121Issue:JANPages:169
Abstract

In this work, the interactions between a representative pyridinium-based ionic liquid (IL) with cyano-functionalized anion ([C4Py][SCN]) and dimethyl sulfoxide (DMSO) were investigated in detail using attenuated total reflection infrared spectroscopy (ATR-FTIR), hydrogen nuclear magnetic resonance (H-1 NMR), and density functional theory (DFT) calculations. It was found that H-bonds are universally involved and play important role for the miscibility of DMSO with [C4Py][SCN] IL and maintain the stability of this system. ATR-FTIR and excess spectroscopy analysis indicated that the H-bonds involving the alkyl C-Hs and C N are strengthened with the addition of DMSO, while the H-bonds involving pyridinium ring C-Hs as well as the H-bonds formed between the [C4Py](+) and [SCN](-) are weakened. The addition of [C4Py][SCN] IL led to the H-bonds involving the C-Hs in DMSO weakened comparing with the associated H-bonds in the pure DMSO system. The results of DFT calculations indicated that the DMSO molecules cannot disrupt the strong Coulombic interaction between the [C4Py](+) and [SCN](-). Natural bond orbital (NBO) analysis further confirmed that the interaction mechanisms of DMSO molecule with the anion and cation are different in nature. These studies will shed light on exploring the applications of ILs as reaction or separation media. (C) 2014 Elsevier Ltd. All rights reserved,

KeywordQuantum Chemical Calculation Hybrid Density Functionals Atr-ftir High-pressure Ionic Liquids Water Hydrogen Bond Imidazolium Excess Infrared Spectroscopy Tetrafluoroborate Spectroscopy Methanol Trifluoroacetate Solvation Cellulose
SubtypeArticle
Subject AreaEngineering, Chemical ; Engineering
DOI10.1016/j.ces.2014.07.024
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000344943900016
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Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/20664
Collection研究所(批量导入)
Corresponding AuthorZhang, SJ
Recommended Citation
GB/T 7714
He, HY,Chen, H,Zheng, YZ,et al. Hydrogen-bonding interactions between a pyridinium-based ionic liquid [C4Py][SCN] and dimethyl sulfoxide[J]. CHEMICAL ENGINEERING SCIENCE,2015,121(JAN):169.
APA He, HY,Chen, H,Zheng, YZ,Zhang, SJ,&Yu, ZW.(2015).Hydrogen-bonding interactions between a pyridinium-based ionic liquid [C4Py][SCN] and dimethyl sulfoxide.CHEMICAL ENGINEERING SCIENCE,121(JAN),169.
MLA He, HY,et al."Hydrogen-bonding interactions between a pyridinium-based ionic liquid [C4Py][SCN] and dimethyl sulfoxide".CHEMICAL ENGINEERING SCIENCE 121.JAN(2015):169.
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