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Experimental and theoretical studies on hydrogen bond-promoted fixation of carbon dioxide and epoxides in cyclic carbonates
Wang, JQ; Sun, J; Cheng, WG; Dong, K; Zhang, XP; Zhang, SJ; Wang, Jin-Quan; Sun, Jian; Cheng, Wei-Guo; Dong, Kun; Zhang, Xiang-Ping; Zhang, Suo-Jiang
2012
Source PublicationPHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN1463-9076
Volume14Issue:31Pages:11021
Abstract

The hydrogen bond donor-promoted fixation of CO2 and epoxides into cyclic carbonates was investigated through experimental and density functional theory studies. A highly effective homogeneous system of 1,2-benzenediol-tetrabutyl ammonium bromide (TBAB) and heterogeneous poly-ionic liquids were developed for the fixation of CO2 into cyclic carbonates via hydrogen bond activation, based on the understanding of the reaction mechanism and catalyst design. The work hence provides a molecular level understanding of the reaction process and forms the basis for the rational design of catalytic systems for the fixation of CO2 into useful organic compounds.

KeywordIonic Liquids Supercritical Conditions Catalytic-activity Propylene-oxide Ethylene-oxide Co2 Cycloaddition Transformation Capture Silica
SubtypeArticle
Subject AreaChemistry, Physical ; Physics, Atomic, Molecular & Chemical ; Chemistry ; Physics
DOI10.1039/c2cp41698k
URL查看原文
Indexed BySCI
Language英语
Funding ProjectNational Basic Research Program of China [2009CB219904] ; National Natural Sciences Foundation of China [21003129, 21036007, 20936005]
WOS IDWOS:000306572600024
Citation statistics
Cited Times:81[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/20716
Collection研究所(批量导入)
Corresponding AuthorZhang, Suo-Jiang
Recommended Citation
GB/T 7714
Wang, JQ,Sun, J,Cheng, WG,et al. Experimental and theoretical studies on hydrogen bond-promoted fixation of carbon dioxide and epoxides in cyclic carbonates[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2012,14(31):11021.
APA Wang, JQ.,Sun, J.,Cheng, WG.,Dong, K.,Zhang, XP.,...&Zhang, Suo-Jiang.(2012).Experimental and theoretical studies on hydrogen bond-promoted fixation of carbon dioxide and epoxides in cyclic carbonates.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,14(31),11021.
MLA Wang, JQ,et al."Experimental and theoretical studies on hydrogen bond-promoted fixation of carbon dioxide and epoxides in cyclic carbonates".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 14.31(2012):11021.
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