Conversion of bis(2-hydroxyethylene terephthalate) into 1,4-cyclohexanedimethanol by selective hydrogenation using RuPtSn/Al2O3
Hou, Danfeng1,2; Xin, Jiayu2; Lu, Xingmei2; Guo, Xiaonan1,2; Dong, Huixian2; Ren, Baozeng1; Zhang, Suojiang2
2016
发表期刊RSC ADVANCES
ISSN2046-2069
卷号6期号:54页码:48737-48744
摘要1,4-Cyclohexanedimethanol (CHDM) is a highly valued and widely used monomer in the polymer industry. Bis(2-hydroxyethylene terephthalate) (BHET), the product of glycolysis of waste PET, is an excellent raw material for the preparation of CHDM. Herein, a series of monometallic, bimetallic and trimetallic supported catalysts were prepared for the one-pot conversion of BHET into CHDM by the impregnation method and good performance was found over trimetallic RuPtSn/Al2O3 catalysts containing various active sites to catalyze the hydrogenation of the phenyl and carbonyl groups. The influences of various reaction parameters including temperature, pressure and time on the hydrogenation reaction were studied, and 100% conversion and 87.1% yield of CHDM were obtained with the trimetallic supported catalyst with Ru/Sn 1.5. Moreover, through the comparison between various methods for the preparation of CHDM, the conversion of BHET into CHDM by the one-pot method is considered one of the most competitive methods.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c6ra04943e
收录类别SCI
语种英语
关键词[WOS]POROUS ALUMINA SPHERES ; SN CATALYSTS ; DIMETHYL TEREPHTHALATE ; SINGLE-STEP ; CROTONALDEHYDE HYDROGENATION ; BENZENE HYDROGENATION ; HIGH-PERFORMANCE ; IONIC LIQUIDS ; GLYCOLYSIS ; POLY(ETHYLENE-TEREPHTHALATE)
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
项目资助者International S&T Cooperation Program of China(2014DFA61670) ; National Natural Science Foundation of China(91434203 ; Key Project of Natural Science Foundation of Beijing of China(2131005) ; CAS/SAFEA International Partnership Program for Creative Research Teams(20140491518) ; 21336002 ; 21476234 ; 21276260 ; 21576269)
WOS记录号WOS:000377257000062
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/20966
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
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GB/T 7714
Hou, Danfeng,Xin, Jiayu,Lu, Xingmei,et al. Conversion of bis(2-hydroxyethylene terephthalate) into 1,4-cyclohexanedimethanol by selective hydrogenation using RuPtSn/Al2O3[J]. RSC ADVANCES,2016,6(54):48737-48744.
APA Hou, Danfeng.,Xin, Jiayu.,Lu, Xingmei.,Guo, Xiaonan.,Dong, Huixian.,...&Zhang, Suojiang.(2016).Conversion of bis(2-hydroxyethylene terephthalate) into 1,4-cyclohexanedimethanol by selective hydrogenation using RuPtSn/Al2O3.RSC ADVANCES,6(54),48737-48744.
MLA Hou, Danfeng,et al."Conversion of bis(2-hydroxyethylene terephthalate) into 1,4-cyclohexanedimethanol by selective hydrogenation using RuPtSn/Al2O3".RSC ADVANCES 6.54(2016):48737-48744.
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