Mixed-Valent Mn-16-Containing Heteropolyanions: Tuning of Oxidation State and Associated Physicochemical Properties
Haider, Ali1; Ibrahim, Masooma1,5; Bassil, Bassem S.1,2; Carey, Akina M.1; Anh Nguyen Viet1; Xing, Xiaolin1; Ayass, Wassim W.1; Minambres, Juan F.1; Liu, Rongji3; Zhang, Guangjin3; Keita, Bineta4; Mereacre, Valeriu5; Powell, Annie K.5,6; Balinski, Kamil7,8; N'Diaye, Alpha T.9; Kuepper, Karsten7,8; Chen, Han-Yi10,11; Stimming, Ulrich10,11,12; Kortz, Ulrich1
2016-03-21
发表期刊INORGANIC CHEMISTRY
ISSN0020-1669
卷号55期号:6页码:2755-2764
摘要The two 16-manganese-containing, Keggin-based 36-tungsto-4-silicates [(Mn10Mn6O6)-Mn-III-O-II(OH)(6)(PO4)(4)(A-alpha-SiW9O34)(4)](28-) (1) and [(Mn4Mn12II)-Mn-III(OH)(12)(PO4)(4)(A-alpha-SiW9O34)(4)](28-) (2) have been prepared by reaction of the trilacunary Keggin precursor [A-alpha-SiW9O34](10-) with either Mn(OOCCH3)(3)center dot 2H(2)O (for 1) or MnCl2 center dot 4H2O (for 2), in aqueous phosphate solution at pH 9. Polyanions 1 and 2 comprise mixed-valent, cationic {(MnMnI6O6)-Mn-III-I-II(OH)(6)}(24+) and {(Mn10Mn6O6)-Mn-III-O-II(OH)(6)(PO4)(4) cores, respectively, encapsulated by four phosphate groups and four {SiW9} units in a tetrahedral fashion. Both polyanions were structurally and compositionally Characterized by single-crystal XRD, IR, therrnogravimetric analysis, and X-ray absorption,, spectroscopy. Furthermore, studies were performed probing, the magnetic, electrochemical, oxidation catalytic, and Li-ion battery performance of 1 and 2.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1021/acs.inorgchem.5b02503
收录类别SCI
语种英语
关键词[WOS]SINGLE-MOLECULE MAGNET ; DAWSON SANDWICH COMPLEXES ; FREE AEROBIC OXIDATION ; TRANSITION-METAL ; CRYSTAL-STRUCTURE ; BUILDING-BLOCKS ; WATER OXIDATION ; ELECTROCHEMICAL GENERATION ; POLYOXOMETALATE CHEMISTRY ; DIMERIC POLYOXOANIONS
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
项目资助者German Science Foundation (DFG)(KO 2288/20-1) ; CMST COST Action(CM1203) ; Jacobs University ; Chinese Academy of Sciences President's International Fellowship Initiative(2015VMA041) ; DAAD ; DFG ; Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT) ; Higher Education Commission of Pakistan ; Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy(DE-AC02-05CH11231) ; National Science Foundation of China(21371173) ; TUM CREATE ; National Research Foundation of Singapore ; Newcastle University
WOS记录号WOS:000372677800013
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/20972
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Jacobs Univ Bremen, Dept Life Sci & Chem, POB 750 561, D-28725 Bremen, Germany
2.Univ Balamand, Dept Chem, Fac Sci, POB 100, Tripoli, Lebanon
3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
4.Univ Paris 11, UMR CNRS 8000, Lab Chim Phys, F-91405 Orsay, France
5.KIT, Inst Nanotechnol, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany
6.KIT, Inst Inorgan Chem, Engesserstr 15, D-76131 Karlsruhe, Germany
7.Univ Osnabruck, Dept Phys, D-49069 Osnabruck, Germany
8.Univ Osnabruck, Ctr Phys & Chem New Mat, D-49069 Osnabruck, Germany
9.Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA
10.TUM CREATE, 1 CREATE Way,10-02 CREATE Tower, Singapore 138602, Singapore
11.Tech Univ Munich, Dept Chem, Lichtenbergstr 4, D-85748 Garching, Germany
12.Newcastle Univ, Sch Chem, Bedson Bldg, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
推荐引用方式
GB/T 7714
Haider, Ali,Ibrahim, Masooma,Bassil, Bassem S.,et al. Mixed-Valent Mn-16-Containing Heteropolyanions: Tuning of Oxidation State and Associated Physicochemical Properties[J]. INORGANIC CHEMISTRY,2016,55(6):2755-2764.
APA Haider, Ali.,Ibrahim, Masooma.,Bassil, Bassem S..,Carey, Akina M..,Anh Nguyen Viet.,...&Kortz, Ulrich.(2016).Mixed-Valent Mn-16-Containing Heteropolyanions: Tuning of Oxidation State and Associated Physicochemical Properties.INORGANIC CHEMISTRY,55(6),2755-2764.
MLA Haider, Ali,et al."Mixed-Valent Mn-16-Containing Heteropolyanions: Tuning of Oxidation State and Associated Physicochemical Properties".INORGANIC CHEMISTRY 55.6(2016):2755-2764.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Mixed-Valent Mn-16-C(2348KB)期刊论文出版稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Haider, Ali]的文章
[Ibrahim, Masooma]的文章
[Bassil, Bassem S.]的文章
百度学术
百度学术中相似的文章
[Haider, Ali]的文章
[Ibrahim, Masooma]的文章
[Bassil, Bassem S.]的文章
必应学术
必应学术中相似的文章
[Haider, Ali]的文章
[Ibrahim, Masooma]的文章
[Bassil, Bassem S.]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Mixed-Valent Mn-16-Containing Heteropolyanions_ Tuning of Oxidation State and Associated Physicochemical Properties.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。