Converting ultrafine silver nanoclusters to monodisperse silver sulfide nanoparticles via a reversible phase transfer protocol | |
Feng, Yan1,2; Yao, Qiaofeng2; Li, Jingguo2; Goswami, Nirmal2; Xie, Jianping2; Yang, Jun1 | |
2016-04-01 | |
Source Publication | NANO RESEARCH
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ISSN | 1998-0124 |
Volume | 9Issue:4Pages:942-950 |
Abstract | To achieve better control of the formation of silver sulfide (Ag2S) nanoparticles, ultrasmall Ag nanoclusters protected by thiolate ligands (Ag-44(SR)(30) and Ag-16(GSH)(9)) are used as precursors, which, via delicate chemistry, can be readily converted to monodisperse Ag2S nanoparticles with controllable sizes (4-16 nm) and switchable solvent affinity (between aqueous and organic solvents). This new synthetic protocol makes use of the atomic monodispersity and rich surface chemistry of Ag nanoclusters and a novel two-phase protocol design, which results in a well-controlled reaction environment for the formation of Ag2S nanoparticles. |
Keyword | Silver Sulfide Nanoparticles Silver Nanoclusters Thiolated Metal Nanoclusters Two-phase Synthesis |
Subtype | Article |
WOS Headings | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1007/s12274-015-0980-y |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | NOBLE-METAL NANOCLUSTERS ; PROTECTED GOLD CLUSTERS ; AU-25 NANOCLUSTERS ; AG2S NANOCRYSTALS ; ATOMIC PRECISION ; QUANTUM DOTS ; REDUCTION ; GROWTH ; SIZE ; COMPLEXES |
WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
WOS Subject | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
Funding Organization | National Natural Science Foundation of China(21173226 ; Ministry of Education, Singapore(R-279-000-409-112) ; 21376247 ; 21573240) |
WOS ID | WOS:000375081400006 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/21026 |
Collection | 多相复杂系统国家重点实验室 |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Natl Univ Singapore, Dept Chem & Biomol Engn, 10 Kent Ridge Crescent, Singapore 119260, Singapore |
Recommended Citation GB/T 7714 | Feng, Yan,Yao, Qiaofeng,Li, Jingguo,et al. Converting ultrafine silver nanoclusters to monodisperse silver sulfide nanoparticles via a reversible phase transfer protocol[J]. NANO RESEARCH,2016,9(4):942-950. |
APA | Feng, Yan,Yao, Qiaofeng,Li, Jingguo,Goswami, Nirmal,Xie, Jianping,&Yang, Jun.(2016).Converting ultrafine silver nanoclusters to monodisperse silver sulfide nanoparticles via a reversible phase transfer protocol.NANO RESEARCH,9(4),942-950. |
MLA | Feng, Yan,et al."Converting ultrafine silver nanoclusters to monodisperse silver sulfide nanoparticles via a reversible phase transfer protocol".NANO RESEARCH 9.4(2016):942-950. |
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Converting ultrafine(2244KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text |
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