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Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts
Song, Yanlei1; Wang, Xincheng1; Qu, Yongshui2; Huang, Chongpin1; Li, Yingxia1; Chen, Biaohua1
2016-04-01
发表期刊CATALYSTS
ISSN2073-4344
卷号6期号:4页码:1
摘要5-Hydroxymethylfurfural (5-HMF), which is derived from numerous industrial biomass resources, has attracted attention in recent years due to its potential as a building block. In this paper, a range of heteropolyacid salts had been investigated for the dehydration of fructose to 5-HMF. CePW12O40 demonstrated the best catalytic activity. Effects of fructose concentration, reaction temperature and reaction time on 5-HMF yield were investigated and optimised through a central composite design and response surface methodology. The optimal 5-HMF yield was 99.40% under the optimized reaction conditions of 5.48 mg/mL fructose loading, 158 degrees C temperature and 164 min reaction time. A kinetic analysis of the fructose conversion was also performed, and the activation energy and pre-exponential factor were obtained.
关键词5-hydroxymethylfurfural Dehydration Fructose Heteropolyacid Salt Response-surface-methodology Optimisation
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.3390/catal6040049
收录类别SCI
语种英语
关键词[WOS]HOT-COMPRESSED WATER ; IONIC LIQUID ; BIO-OIL ; CONVERSION ; GLUCOSE ; BIOMASS ; CHEMICALS ; 5-HYDROXYMETHYL-2-FURALDEHYDE ; TRANSFORMATION ; OPTIMIZATION
WOS研究方向Chemistry
WOS类目Chemistry, Physical
项目资助者National Natural Science Foundation of China(21476021)
WOS记录号WOS:000375210900001
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21030
专题生化工程国家重点实验室
作者单位1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China
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Song, Yanlei,Wang, Xincheng,Qu, Yongshui,et al. Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts[J]. CATALYSTS,2016,6(4):1.
APA Song, Yanlei,Wang, Xincheng,Qu, Yongshui,Huang, Chongpin,Li, Yingxia,&Chen, Biaohua.(2016).Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts.CATALYSTS,6(4),1.
MLA Song, Yanlei,et al."Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts".CATALYSTS 6.4(2016):1.
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