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Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts
Song, Yanlei1; Wang, Xincheng1; Qu, Yongshui2; Huang, Chongpin1; Li, Yingxia1; Chen, Biaohua1
2016-04-01
Source PublicationCATALYSTS
ISSN2073-4344
Volume6Issue:4Pages:1
Abstract5-Hydroxymethylfurfural (5-HMF), which is derived from numerous industrial biomass resources, has attracted attention in recent years due to its potential as a building block. In this paper, a range of heteropolyacid salts had been investigated for the dehydration of fructose to 5-HMF. CePW12O40 demonstrated the best catalytic activity. Effects of fructose concentration, reaction temperature and reaction time on 5-HMF yield were investigated and optimised through a central composite design and response surface methodology. The optimal 5-HMF yield was 99.40% under the optimized reaction conditions of 5.48 mg/mL fructose loading, 158 degrees C temperature and 164 min reaction time. A kinetic analysis of the fructose conversion was also performed, and the activation energy and pre-exponential factor were obtained.
Keyword5-hydroxymethylfurfural Dehydration Fructose Heteropolyacid Salt Response-surface-methodology Optimisation
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.3390/catal6040049
Indexed BySCI
Language英语
WOS KeywordHOT-COMPRESSED WATER ; IONIC LIQUID ; BIO-OIL ; CONVERSION ; GLUCOSE ; BIOMASS ; CHEMICALS ; 5-HYDROXYMETHYL-2-FURALDEHYDE ; TRANSFORMATION ; OPTIMIZATION
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
Funding OrganizationNational Natural Science Foundation of China(21476021)
WOS IDWOS:000375210900001
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/21030
Collection生化工程国家重点实验室
Affiliation1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Song, Yanlei,Wang, Xincheng,Qu, Yongshui,et al. Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts[J]. CATALYSTS,2016,6(4):1.
APA Song, Yanlei,Wang, Xincheng,Qu, Yongshui,Huang, Chongpin,Li, Yingxia,&Chen, Biaohua.(2016).Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts.CATALYSTS,6(4),1.
MLA Song, Yanlei,et al."Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts".CATALYSTS 6.4(2016):1.
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