CAS OpenIR  > 生化工程国家重点实验室
One-pot conversion of disaccharide into 5-hydroxymethylfurfural catalyzed by imidazole ionic liquid
Qu, Yongshui1; Li, Li1,2; Wei, Quanyuan3; Huang, Chongpin2; Oleskowicz-Popiel, Piotr4; Xu, Jian1
2016-05-16
发表期刊SCIENTIFIC REPORTS
ISSN2045-2322
卷号6期号:MAY页码:26067
摘要Conversion of carbohydrate into 5-hydroxymethylfurfural (5-HMF), a versatile, key renewable platform compound is regarded as an important transformation in biomass-derived carbohydrate chemistry. A variety of ILs, not only acidic but also alkaline ILs, were synthesized and used as catalyst in the production of 5-HMF from disaccharide. Several factors including reaction temperature, IL dosage, solvent and reaction time, were found to influence the yield of 5-HMF from cellobiose. Of the ILs tested, hydroxy-functionalized ionic liquid (IL), 1-hydroxyethyl-3-methylimidazolium tetrafluoroborate ([AEMIM] BF4) showed the highest catalytic activity and selectivity. 5-HMF yield of 68.71% from sucrose was obtained after 6 hrs at 160 degrees C. At the same condition with cellobiose as substrate, 5-HMF yield was 24.73%. In addition, 5-HMF also exhibited good stablity in this reaction system. Moreover, a kinetic analysis was carried out in both acidic and alkaline IL-catalyzed system, suggesting main side reaction in the conversion of fructose catalyzed by acidic and alkaline IL was polymerization of fructose and 5-HMF degradation, respectively.
文章类型Article
WOS标题词Science & Technology
DOI10.1038/srep26067
收录类别SCI
语种英语
关键词[WOS]AEROBIC OXIDATION ; ACID ; DEHYDRATION ; FRUCTOSE ; EFFICIENT ; CO2 ; BASE ; HMF
WOS研究方向Science & Technology - Other Topics
WOS类目Multidisciplinary Sciences
项目资助者National Natural Science Foundation of China(21276259) ; International (Regional) Cooperation And Exchange Project(21450110062) ; National High Technology Research and Development Program of China (863 Program)(2012AA022301) ; University-Institute Cooperation Funds from University of the Chinese Academy of Sciences(Y552017Y00) ; Technology Plan Projects of Beijing(Z14110000061404)
WOS记录号WOS:000375924200001
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21053
专题生化工程国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
2.Beijing Univ Chem Technol, Beijing 100029, Peoples R China
3.Beijing Municipal Res Acad Environm Protect, Beijing 100037, Peoples R China
4.Poznan Univ Tech, Fac Civil & Environm Engn, Inst Environm Engn, Berdychowo 4, PL-60965 Poznan, Poland
推荐引用方式
GB/T 7714
Qu, Yongshui,Li, Li,Wei, Quanyuan,et al. One-pot conversion of disaccharide into 5-hydroxymethylfurfural catalyzed by imidazole ionic liquid[J]. SCIENTIFIC REPORTS,2016,6(MAY):26067.
APA Qu, Yongshui,Li, Li,Wei, Quanyuan,Huang, Chongpin,Oleskowicz-Popiel, Piotr,&Xu, Jian.(2016).One-pot conversion of disaccharide into 5-hydroxymethylfurfural catalyzed by imidazole ionic liquid.SCIENTIFIC REPORTS,6(MAY),26067.
MLA Qu, Yongshui,et al."One-pot conversion of disaccharide into 5-hydroxymethylfurfural catalyzed by imidazole ionic liquid".SCIENTIFIC REPORTS 6.MAY(2016):26067.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
One-pot conversion o(658KB)期刊论文出版稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Qu, Yongshui]的文章
[Li, Li]的文章
[Wei, Quanyuan]的文章
百度学术
百度学术中相似的文章
[Qu, Yongshui]的文章
[Li, Li]的文章
[Wei, Quanyuan]的文章
必应学术
必应学术中相似的文章
[Qu, Yongshui]的文章
[Li, Li]的文章
[Wei, Quanyuan]的文章
相关权益政策
暂无数据
收藏/分享
文件名: One-pot conversion of disaccharide into 5-hydroxymethylfurfural catalyzed by imidazole ionic liquid.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。