| The Construction of an Aqueous Two-Phase System to Solve Weak-Aggregation of Gigaporous Poly(Styrene-Divinyl Benzene) Microspheres | |
| Zhang, Donglai1,2; Zhou, Weiqing1; Li, Juan1; Mi, Yace1,2; Su, Zhiguo1; Ma, Guanghui1 | |
| 2016-05-01 | |
| 发表期刊 | POLYMERS
 |
| ISSN | 2073-4360 |
| 卷号 | 8期号:5页码:142 |
| 摘要 | Gigaporous poly(styrene-divinyl benzene) microspheres made via the surfactant reverse micelles swelling method had a controllable pore size of 100-500 nm. These microspheres had unique advantages in biomacromolecule separation and enzymes immobilization. However, the obtained microspheres adhered to each other in the preparation process. Though the weak aggregation could be re-dispersed easily by mechanical force, it will be difficult to scale up. By analyzing the formation mechanism of the aggregates, a method was presented to rebuild the interface between the internal aqueous channel and the external continuous phase by constructing an aqueous two-phase system (ATPS). Based on the ATPS, the method of emulsification, stirring speed, and surfactant concentration in oil phase were optimized. Under the optimum condition (screen emulsification method, 120 rpm for polymerization and 55% surfactant), the microspheres with a controllable particle size of 10-40 m and a pore size of about 150 nm were obtained. This new method could significantly decrease the weak-aggregation of microspheres. |
| 关键词 | Gigaporous Microspheres Weak-aggregation Aqueous Two-phase System |
| 文章类型 | Article |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.3390/polym8050142 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | MEMBRANE EMULSIFICATION TECHNIQUE ; MICELLES SWELLING METHOD ; COMPOSITE MICROSPHERES ; BINDING-CAPACITY ; PORE STRUCTURE ; PARTICLES ; EMULSION ; CHROMATOGRAPHY ; MEDIA ; POLYMERIZATION |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 项目资助者 | National Natural Science Foundation of China(21336010) ; National Science and Technology Support Program(2012AA02A406) |
| WOS记录号 | WOS:000377795200002 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.ipe.ac.cn/handle/122111/21160 |
| 专题 | 生化工程国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Donglai,Zhou, Weiqing,Li, Juan,et al. The Construction of an Aqueous Two-Phase System to Solve Weak-Aggregation of Gigaporous Poly(Styrene-Divinyl Benzene) Microspheres[J]. POLYMERS,2016,8(5):142. |
| APA | Zhang, Donglai,Zhou, Weiqing,Li, Juan,Mi, Yace,Su, Zhiguo,&Ma, Guanghui.(2016).The Construction of an Aqueous Two-Phase System to Solve Weak-Aggregation of Gigaporous Poly(Styrene-Divinyl Benzene) Microspheres.POLYMERS,8(5),142. |
| MLA | Zhang, Donglai,et al."The Construction of an Aqueous Two-Phase System to Solve Weak-Aggregation of Gigaporous Poly(Styrene-Divinyl Benzene) Microspheres".POLYMERS 8.5(2016):142. |
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| The Construction of （5089KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 浏览 请求全文 | |
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论