High-efficient extraction of vanadium and its application in the utilization of the chromium-bearing vanadium slag
Ning, Pengge1,2; Lin, Xiao1,2; Wang, Xiangyang1; Cao, Hongbin1,2
2016-10-01
发表期刊CHEMICAL ENGINEERING JOURNAL
ISSN1385-8947
卷号301期号:OCT页码:132-138
摘要The high-efficient extraction of vanadium using primary amine and its application in the utilization of the chromium-bearing vanadium slag (V-Cr slag) were studied in this work. The extraction mechanism and the possible difficulties in the application were both considered. From the results, the extraction percentage of vanadium using free primary amine with the hydrogen bond association mechanism is higher than that in the acidic environment by primary amine salts. The inorganic ions and other impurities existing in the system were all considered to research for the continuous operation of the extraction. Furthermore, the viscosities of the fresh organic phase and the recycled organic phase were determined using the extractant not only N1923 but also LK-N21, where the viscosity of the latter system increased slightly during the recycled process of the extractant. Based on the above results, the pilot and the commercial experiment were carried out. In the large-scale experiment, the vanadium was extracted and the product of 99.5 wt.% vanadium pentoxide was obtained, and the mass loss of the extractant was only 0.1%. (C) 2016 Published by Elsevier B.V.
关键词Vanadium Chromium Waste Slag Extraction Application
文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1016/j.cej.2016.03.066
收录类别SCI
语种英语
关键词[WOS]PRIMARY AMINE ; SYNERGISTIC EXTRACTION ; SOLVENT-EXTRACTION ; SEPARATION ; MEMBRANE ; REMOVAL ; CR(VI) ; V(V)
WOS研究方向Engineering
WOS类目Engineering, Environmental ; Engineering, Chemical
项目资助者National Key Technology Support Program of China(2015BAB021305) ; National Natural Science Foundation(51425405)
WOS记录号WOS:000378470700016
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21175
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Res Ctr Proc Pollut Control Beijing, Beijing 100190, Peoples R China
2.Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing, Peoples R China
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GB/T 7714
Ning, Pengge,Lin, Xiao,Wang, Xiangyang,et al. High-efficient extraction of vanadium and its application in the utilization of the chromium-bearing vanadium slag[J]. CHEMICAL ENGINEERING JOURNAL,2016,301(OCT):132-138.
APA Ning, Pengge,Lin, Xiao,Wang, Xiangyang,&Cao, Hongbin.(2016).High-efficient extraction of vanadium and its application in the utilization of the chromium-bearing vanadium slag.CHEMICAL ENGINEERING JOURNAL,301(OCT),132-138.
MLA Ning, Pengge,et al."High-efficient extraction of vanadium and its application in the utilization of the chromium-bearing vanadium slag".CHEMICAL ENGINEERING JOURNAL 301.OCT(2016):132-138.
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