Effect of the properties of MnOx/activated carbon and flue gas components on Hg-0 removal at low temperature
Tong, Li1,2; Xu, Wenqing1; Yang, Yang1,2; Liu, Ruihui1; Wu, Yinghong1,2; Zhu, Tingyu1
2016
发表期刊RSC ADVANCES
ISSN2046-2069
卷号6期号:82页码:78743-78749
摘要

Manganese oxide loaded on activated carbon (Mn/AC) was synthesized using an impregnation method, and its capacity for Hg-0 removal in simulated flue gas was investigated at 120 degrees C. The Hg-0 removal performance was significantly enhanced by manganese oxide. The effects of the Mn loading on Hg-0 removal were evaluated. X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) were employed to characterize the samples. In addition, the effects of individual flue gas components, including SO2, NO and HCl, on the Hg-0 removal performance over the Mn/AC sorbent were investigated. The results indicated that 10% Mn/AC was the optimal sorbent under the simulated flue gas conditions. The XRD and BET analyses indicated that the Mn3O4 crystal particles and surface area were the primary factors that contributed to Hg-0 removal. The competitive adsorption and formation of Mn(SO4)(x) were the primary reasons that SO2 inhibits Hg-0 removal. In a pure N-2 atmosphere, a low concentration of NO decreased the Hg-0 removal due to consumption of active oxygen species. However, a high concentration of NO promoted Hg-0 removal due to the formation of N-containing active species that were generated on the sample surface. The Mn/AC sample remained highly active toward Hg-0 removal in the presence of HCl due to reaction with active chlorine species.

文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c6ra16763b
收录类别SCI
语种英语
关键词[WOS]GASEOUS ELEMENTAL MERCURY ; MANGANESE OXIDE/TITANIA MATERIALS ; SELECTIVE CATALYTIC-REDUCTION ; ACTIVATED CARBON ; OXIDATION ; ADSORPTION ; OXIDE ; SORBENTS ; CAPTURE ; NO
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
项目资助者National Basic Research Program (973) of China(2013CB430005) ; National Hi-Tech Research and Development Program (863) of China(2013AA065501) ; Special Research Funding for Public Benefit Industries from National Ministry of Environmental Protection(201309018)
WOS记录号WOS:000382539300060
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21316
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Beijing Engn Res Ctr Proc Pollut Control, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Tong, Li,Xu, Wenqing,Yang, Yang,et al. Effect of the properties of MnOx/activated carbon and flue gas components on Hg-0 removal at low temperature[J]. RSC ADVANCES,2016,6(82):78743-78749.
APA Tong, Li,Xu, Wenqing,Yang, Yang,Liu, Ruihui,Wu, Yinghong,&Zhu, Tingyu.(2016).Effect of the properties of MnOx/activated carbon and flue gas components on Hg-0 removal at low temperature.RSC ADVANCES,6(82),78743-78749.
MLA Tong, Li,et al."Effect of the properties of MnOx/activated carbon and flue gas components on Hg-0 removal at low temperature".RSC ADVANCES 6.82(2016):78743-78749.
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