Controllable Synthesis of Silver Dendrites via an Interplay of Chemical Diffusion and Reaction | |
Liu, Wei1,2; Yang, Tao1,3; Liu, Jianmei1,4; Che, Ping2; Han, Yongsheng1 | |
2016-08-03 | |
Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
![]() |
ISSN | 0888-5885 |
Volume | 55Issue:30Pages:8319-8326 |
Abstract | Here we report a study on the role of chemical diffusion and reaction on the morphology evolution of silver particles. Electrochemical reaction is employed to synthesize silver particles. The reaction rate is regulated by current density while the diffusion rate of silver ions is regulated by the viscosity of solution. Silver dendritic particles are largely synthesized at various diffusion and reaction conditions. At a high reaction rate, silver dendrites are formed at the medium diffusion rates of silver ions while the dendritic structures are only formed at an extremely low diffusion rate of silver ions when the reaction proceeds slowly. Therefore, the interplay of diffusion and reaction plays a key role on the structure development of dendrites because the interplay determines the chemical distribution on the growth front of crystals. Once a chemical concentration gradient is established at the growth front, the dendritic structures is triggered. |
Subtype | Article |
WOS Headings | Science & Technology ; Technology |
DOI | 10.1021/acs.iecr.6b01227 |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | REPLACEMENT REACTION ; ELECTROLESS DEPOSITION ; CATALYTIC-REDUCTION ; SURFACE ; NANOPARTICLES ; GROWTH ; NANOCRYSTALS ; COMPROMISE ; COPPER ; FILMS |
WOS Research Area | Engineering |
WOS Subject | Engineering, Chemical |
Funding Organization | Chinese Academy of Sciences ; State Key Laboratory of Multiphase Complex Systems(MPCS-2014-D-05) ; National Natural Science Foundation of China(U1462130 ; 91534123) |
WOS ID | WOS:000381062800010 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/21431 |
Collection | 多相复杂系统国家重点实验室 |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China |
Recommended Citation GB/T 7714 | Liu, Wei,Yang, Tao,Liu, Jianmei,et al. Controllable Synthesis of Silver Dendrites via an Interplay of Chemical Diffusion and Reaction[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2016,55(30):8319-8326. |
APA | Liu, Wei,Yang, Tao,Liu, Jianmei,Che, Ping,&Han, Yongsheng.(2016).Controllable Synthesis of Silver Dendrites via an Interplay of Chemical Diffusion and Reaction.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,55(30),8319-8326. |
MLA | Liu, Wei,et al."Controllable Synthesis of Silver Dendrites via an Interplay of Chemical Diffusion and Reaction".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 55.30(2016):8319-8326. |
Files in This Item: | ||||||
File Name/Size | DocType | Version | Access | License | ||
Controllable Synthes(9427KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment