CAS OpenIR  > 多相复杂系统国家重点实验室
Kinetic and Reactive Distillation for Acrylic Acid Synthesis via Transesterification
Zuo, Cuncun1; Ge, Tingting2; Li, Chunshan1; Cao, Shasha1; Zhang, Suojiang1
2016-08-03
发表期刊INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
卷号55期号:30页码:8281-8291
摘要

Reaction distillation was first used for the process of acrylic acid synthesis through transesterification of methyl acrylate with acetic acid using a strongly acidic cationic exchange resin catalyst (NKC-9). Pseudo-homogeneous (P-H) and Langmuir-Hinshelwood (L-H) heterogeneous kinetic models were presented and fitted with the experimental data obtained from the batch reaction. The key factors of the heterogeneous kinetic model were the four components' adsorption equilibrium constants on the catalyst surface, and they were determined by adsorption experiments. The activity coefficients were calculated using the NRTL method. The catalyst stability was evaluated in a fixed-bed reactor. Catalyst activity showed no obvious decrease after 1000 h of running. A reactive distillation column for acrylic acid synthesis was proposed and designed with process simulation.

文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1021/acs.iecr.6b01128
收录类别SCI
语种英语
关键词[WOS]ION-EXCHANGE-RESIN ; METHYL ACETATE ; ACETIC-ACID ; DIMETHYL CARBONATE ; SEPARATION PROCESS ; ESTERIFICATION ; CATALYSTS ; METHANOL ; ADSORPTION ; ALCOHOL
WOS研究方向Engineering
WOS类目Engineering, Chemical
项目资助者National Program on Key Basic Research Project(2015CB251401) ; National Science Fund for Excellent Young Scholars(21422607) ; National Natural Science Foundation of China(91434203) ; CAS/SAFEA International Partnership Program for Creative Research Teams
WOS记录号WOS:000381062800006
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21433
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Gr, Beijing 100190, Peoples R China
2.China Univ Min & Technol Beijing, Sch Chem & Environm Engn, Beijing 100083, Peoples R China
推荐引用方式
GB/T 7714
Zuo, Cuncun,Ge, Tingting,Li, Chunshan,et al. Kinetic and Reactive Distillation for Acrylic Acid Synthesis via Transesterification[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2016,55(30):8281-8291.
APA Zuo, Cuncun,Ge, Tingting,Li, Chunshan,Cao, Shasha,&Zhang, Suojiang.(2016).Kinetic and Reactive Distillation for Acrylic Acid Synthesis via Transesterification.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,55(30),8281-8291.
MLA Zuo, Cuncun,et al."Kinetic and Reactive Distillation for Acrylic Acid Synthesis via Transesterification".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 55.30(2016):8281-8291.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Anionic Clusters Enh(2102KB)期刊论文出版稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zuo, Cuncun]的文章
[Ge, Tingting]的文章
[Li, Chunshan]的文章
百度学术
百度学术中相似的文章
[Zuo, Cuncun]的文章
[Ge, Tingting]的文章
[Li, Chunshan]的文章
必应学术
必应学术中相似的文章
[Zuo, Cuncun]的文章
[Ge, Tingting]的文章
[Li, Chunshan]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Anionic Clusters Enhanced Catalytic Performance of Protic Acid Ionic Liquids for Isobutane Alkylation.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。