Kinetic and Reactive Distillation for Acrylic Acid Synthesis via Transesterification | |
Zuo, Cuncun1; Ge, Tingting2; Li, Chunshan1; Cao, Shasha1; Zhang, Suojiang1 | |
2016-08-03 | |
Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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ISSN | 0888-5885 |
Volume | 55Issue:30Pages:8281-8291 |
Abstract | Reaction distillation was first used for the process of acrylic acid synthesis through transesterification of methyl acrylate with acetic acid using a strongly acidic cationic exchange resin catalyst (NKC-9). Pseudo-homogeneous (P-H) and Langmuir-Hinshelwood (L-H) heterogeneous kinetic models were presented and fitted with the experimental data obtained from the batch reaction. The key factors of the heterogeneous kinetic model were the four components' adsorption equilibrium constants on the catalyst surface, and they were determined by adsorption experiments. The activity coefficients were calculated using the NRTL method. The catalyst stability was evaluated in a fixed-bed reactor. Catalyst activity showed no obvious decrease after 1000 h of running. A reactive distillation column for acrylic acid synthesis was proposed and designed with process simulation. |
Subtype | Article |
WOS Headings | Science & Technology ; Technology |
DOI | 10.1021/acs.iecr.6b01128 |
Indexed By | SCI |
Language | 英语 |
WOS Keyword | ION-EXCHANGE-RESIN ; METHYL ACETATE ; ACETIC-ACID ; DIMETHYL CARBONATE ; SEPARATION PROCESS ; ESTERIFICATION ; CATALYSTS ; METHANOL ; ADSORPTION ; ALCOHOL |
WOS Research Area | Engineering |
WOS Subject | Engineering, Chemical |
Funding Organization | National Program on Key Basic Research Project(2015CB251401) ; National Science Fund for Excellent Young Scholars(21422607) ; National Natural Science Foundation of China(91434203) ; CAS/SAFEA International Partnership Program for Creative Research Teams |
WOS ID | WOS:000381062800006 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/21433 |
Collection | 多相复杂系统国家重点实验室 |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Gr, Beijing 100190, Peoples R China 2.China Univ Min & Technol Beijing, Sch Chem & Environm Engn, Beijing 100083, Peoples R China |
Recommended Citation GB/T 7714 | Zuo, Cuncun,Ge, Tingting,Li, Chunshan,et al. Kinetic and Reactive Distillation for Acrylic Acid Synthesis via Transesterification[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2016,55(30):8281-8291. |
APA | Zuo, Cuncun,Ge, Tingting,Li, Chunshan,Cao, Shasha,&Zhang, Suojiang.(2016).Kinetic and Reactive Distillation for Acrylic Acid Synthesis via Transesterification.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,55(30),8281-8291. |
MLA | Zuo, Cuncun,et al."Kinetic and Reactive Distillation for Acrylic Acid Synthesis via Transesterification".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 55.30(2016):8281-8291. |
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Anionic Clusters Enh(2102KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | Application Full Text |
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