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Thermodynamics Study on the Separation Process of Cresols from Hexane via Deep Eutectic Solvent Formation
Jiao, Tiantian1,2; Wang, Hongyan1,2; Dai, Fei1,2; Li, Chunshan1; Zhang, Suojiang1
2016-08-17
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume55Issue:32Pages:8848-8857
Abstract

Phenolic compounds could be separated through their formation of deep eutectic solvent (DES). This process was different from normal liquid liquid extraction and was more efficient and environmental. In this work, the thermodynamic process of this kind of separation was studied. Ternary liquid liquid equilibrium data were systematically measured at atmospheric pressure and temperatures from 303.15 to 313.15 K. The experimental data were regressed by NRTL and UNIQUAC models, and the validated results revealed that NRTL model were more consistent with experimental data. The above mentioned parameters could be used to predict ternary mixture interactions and then applied in subsequent design and optimization of the separation process of corresponding systems. This extraction process was further optimized using Aspen Plus with NRTL as thermodynamic model. The simulation results were in good agreement with the experimental outcomes.

SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1021/acs.iecr.6b00649
Indexed BySCI
Language英语
WOS KeywordLIQUID-LIQUID-EXTRACTION ; ATOMIC-FORCE MICROSCOPY ; IONIC LIQUID ; CHOLINE CHLORIDE ; PHASE-EQUILIBRIA ; POTENTIAL USE ; COAL-TAR ; OIL ; BIODIESEL ; AROMATICS
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationStrategic Priority Research Program of the Chinese Academy of Sciences(XDA0702100) ; National Basic Research Program of China (973 Program)(2014CB744306) ; Key Program of Natural Science Foundation of China(91434203) ; External Cooperation Program of BIC, Chinese Academy of Science(GJHZ201306) ; National Science Fund for Excellent Young Scholars(21422607)
WOS IDWOS:000381715500017
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/21435
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Jiao, Tiantian,Wang, Hongyan,Dai, Fei,et al. Thermodynamics Study on the Separation Process of Cresols from Hexane via Deep Eutectic Solvent Formation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2016,55(32):8848-8857.
APA Jiao, Tiantian,Wang, Hongyan,Dai, Fei,Li, Chunshan,&Zhang, Suojiang.(2016).Thermodynamics Study on the Separation Process of Cresols from Hexane via Deep Eutectic Solvent Formation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,55(32),8848-8857.
MLA Jiao, Tiantian,et al."Thermodynamics Study on the Separation Process of Cresols from Hexane via Deep Eutectic Solvent Formation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 55.32(2016):8848-8857.
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