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Thermodynamics Study on the Separation Process of Cresols from Hexane via Deep Eutectic Solvent Formation
Jiao, Tiantian1,2; Wang, Hongyan1,2; Dai, Fei1,2; Li, Chunshan1; Zhang, Suojiang1
2016-08-17
发表期刊INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
卷号55期号:32页码:8848-8857
摘要

Phenolic compounds could be separated through their formation of deep eutectic solvent (DES). This process was different from normal liquid liquid extraction and was more efficient and environmental. In this work, the thermodynamic process of this kind of separation was studied. Ternary liquid liquid equilibrium data were systematically measured at atmospheric pressure and temperatures from 303.15 to 313.15 K. The experimental data were regressed by NRTL and UNIQUAC models, and the validated results revealed that NRTL model were more consistent with experimental data. The above mentioned parameters could be used to predict ternary mixture interactions and then applied in subsequent design and optimization of the separation process of corresponding systems. This extraction process was further optimized using Aspen Plus with NRTL as thermodynamic model. The simulation results were in good agreement with the experimental outcomes.

文章类型Article
WOS标题词Science & Technology ; Technology
DOI10.1021/acs.iecr.6b00649
收录类别SCI
语种英语
关键词[WOS]LIQUID-LIQUID-EXTRACTION ; ATOMIC-FORCE MICROSCOPY ; IONIC LIQUID ; CHOLINE CHLORIDE ; PHASE-EQUILIBRIA ; POTENTIAL USE ; COAL-TAR ; OIL ; BIODIESEL ; AROMATICS
WOS研究方向Engineering
WOS类目Engineering, Chemical
项目资助者Strategic Priority Research Program of the Chinese Academy of Sciences(XDA0702100) ; National Basic Research Program of China (973 Program)(2014CB744306) ; Key Program of Natural Science Foundation of China(91434203) ; External Cooperation Program of BIC, Chinese Academy of Science(GJHZ201306) ; National Science Fund for Excellent Young Scholars(21422607)
WOS记录号WOS:000381715500017
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21435
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
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GB/T 7714
Jiao, Tiantian,Wang, Hongyan,Dai, Fei,et al. Thermodynamics Study on the Separation Process of Cresols from Hexane via Deep Eutectic Solvent Formation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2016,55(32):8848-8857.
APA Jiao, Tiantian,Wang, Hongyan,Dai, Fei,Li, Chunshan,&Zhang, Suojiang.(2016).Thermodynamics Study on the Separation Process of Cresols from Hexane via Deep Eutectic Solvent Formation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,55(32),8848-8857.
MLA Jiao, Tiantian,et al."Thermodynamics Study on the Separation Process of Cresols from Hexane via Deep Eutectic Solvent Formation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 55.32(2016):8848-8857.
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