CAS OpenIR  > 多相复杂系统国家重点实验室
Solvent effect on the debromination/dehydrobromination of bromo-damascone
Cheng, Ying-Ying2; Ren, Tian-Lu1; Xu, Bao-Hua1; Tao, Hai-Sheng2; Zhang, Suo-Jiang1
2016-11-01
发表期刊FLAVOUR AND FRAGRANCE JOURNAL
ISSN0882-5734
卷号31期号:6页码:420-428
摘要

The dehydrogenative synthesis of -damascenone from -damascone via the related allyl bromide intermediate was studied in depth. The requisite dehydrobromination thereof was found strongly solvent system dependent. Under respective conditions, the product was identified as dehydrogenation-derived a, 4-alkoxy-derived b and 4-oxo-derived c, accordingly. In addition, the conversion from b to a was successfully accomplished, thereby offering an alternative access (with one step more) to reach -damascenone. Copyright (c) 2016 John Wiley & Sons, Ltd.

关键词Beta-damascenone Solvent Effect Substitution Allyl Bromide Dehydrobromination
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Life Sciences & Biomedicine
DOI10.1002/ffj.3332
收录类别SCI
语种英语
关键词[WOS]BETA-DAMASCENONE ; ALPHA-DAMASCONE ; CHEMOSELECTIVE OXIDATION ; IONONE ; IDENTIFICATION ; SULFOXIDE ; DMSO ; DERIVATIVES ; PRECURSOR ; ALCOHOLS
WOS研究方向Chemistry ; Food Science & Technology
WOS类目Chemistry, Applied ; Food Science & Technology
项目资助者973 Program(2015CB251401) ; National Natural Science Foundation of China(21476240) ; International Cooperation and Exchange of the National Natural Science Foundation of China(51561145020) ; Instrument Developing Project of the Chinese Academy of Sciences(YZ201521) ; CAS (Chinese Academy of Sciences) 100-Talent Program
WOS记录号WOS:000385712600002
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21569
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Beijing Key Lab Ionic Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China
2.Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu, Peoples R China
推荐引用方式
GB/T 7714
Cheng, Ying-Ying,Ren, Tian-Lu,Xu, Bao-Hua,et al. Solvent effect on the debromination/dehydrobromination of bromo-damascone[J]. FLAVOUR AND FRAGRANCE JOURNAL,2016,31(6):420-428.
APA Cheng, Ying-Ying,Ren, Tian-Lu,Xu, Bao-Hua,Tao, Hai-Sheng,&Zhang, Suo-Jiang.(2016).Solvent effect on the debromination/dehydrobromination of bromo-damascone.FLAVOUR AND FRAGRANCE JOURNAL,31(6),420-428.
MLA Cheng, Ying-Ying,et al."Solvent effect on the debromination/dehydrobromination of bromo-damascone".FLAVOUR AND FRAGRANCE JOURNAL 31.6(2016):420-428.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Cheng_et_al-2016-Fla(1078KB)期刊论文出版稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Cheng, Ying-Ying]的文章
[Ren, Tian-Lu]的文章
[Xu, Bao-Hua]的文章
百度学术
百度学术中相似的文章
[Cheng, Ying-Ying]的文章
[Ren, Tian-Lu]的文章
[Xu, Bao-Hua]的文章
必应学术
必应学术中相似的文章
[Cheng, Ying-Ying]的文章
[Ren, Tian-Lu]的文章
[Xu, Bao-Hua]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Cheng_et_al-2016-Flavour_and_Fragrance_Journal.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。