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Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization
Yu Tian1; Xu Chengnan1; Yu Yuan1; Zhao Feifei1; Pan Yiting1; Liu Cai1; Huang Yongdong2; Zhang Rongyue1
2016-09-10
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume37Issue:9Pages:1740-1743
Abstract

The gigaporous microspheres based on a copolymer of glycidyl methacrylate and ethylene dimethacrylate were prepared by atom transfer radical polymerization(ATRP). The microspheres were characterized by Fourier transform infrared spectrometer, scanning electronic microscopy and mercury intrusion porosimetry. The results indicated that the microspheres by ATRP showed larger size pore and surface than those by conventional free radical polymerization (CFRP). It was observed from the morphology of the microspheres that the smaller size of particles (100-400 nm) formed the skeleton of microspheres by ATRP than CFRP method (1000 nm). Meanwhile the size of these particles by ATRP was well-distributed in comparison with CFRP. These microspheres by ATRP showed good potential in rapid separation of proteins.

KeywordHigh Through-put Separation Support Atom Transfer Radical Polymerization Gigaporous Polymer Microsphere
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.7503/cjcu20160196
Indexed BySCI
Language英语
WOS KeywordA AFFINITY SORBENTS ; CHROMATOGRAPHY ; METHACRYLATE ; PERFORMANCE ; MONOLITH ; HPLC ; ATRP
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
Funding OrganizationBeijing Natural Science Foundation, China(2162013) ; National Natural Science Foundation of China(51103158) ; Breeding Project of Outstanding Young Teachers and Management Backbones, China(080318620081/037) ; Cross Training Programme for High Level Graduate in Beijing Universities, China(201507 ; Undergraduate Research Training Program, China(2016J00079) ; 201506)
WOS IDWOS:000384967000023
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/21621
Collection生化工程国家重点实验室
Affiliation1.Beijing Inst Petrochem Technol, Dept Chem Engn, Beijing 102617, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yu Tian,Xu Chengnan,Yu Yuan,et al. Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2016,37(9):1740-1743.
APA Yu Tian.,Xu Chengnan.,Yu Yuan.,Zhao Feifei.,Pan Yiting.,...&Zhang Rongyue.(2016).Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,37(9),1740-1743.
MLA Yu Tian,et al."Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 37.9(2016):1740-1743.
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