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Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization
Yu Tian1; Xu Chengnan1; Yu Yuan1; Zhao Feifei1; Pan Yiting1; Liu Cai1; Huang Yongdong2; Zhang Rongyue1
2016-09-10
发表期刊CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
卷号37期号:9页码:1740-1743
摘要

The gigaporous microspheres based on a copolymer of glycidyl methacrylate and ethylene dimethacrylate were prepared by atom transfer radical polymerization(ATRP). The microspheres were characterized by Fourier transform infrared spectrometer, scanning electronic microscopy and mercury intrusion porosimetry. The results indicated that the microspheres by ATRP showed larger size pore and surface than those by conventional free radical polymerization (CFRP). It was observed from the morphology of the microspheres that the smaller size of particles (100-400 nm) formed the skeleton of microspheres by ATRP than CFRP method (1000 nm). Meanwhile the size of these particles by ATRP was well-distributed in comparison with CFRP. These microspheres by ATRP showed good potential in rapid separation of proteins.

关键词High Through-put Separation Support Atom Transfer Radical Polymerization Gigaporous Polymer Microsphere
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.7503/cjcu20160196
收录类别SCI
语种英语
关键词[WOS]A AFFINITY SORBENTS ; CHROMATOGRAPHY ; METHACRYLATE ; PERFORMANCE ; MONOLITH ; HPLC ; ATRP
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
项目资助者Beijing Natural Science Foundation, China(2162013) ; National Natural Science Foundation of China(51103158) ; Breeding Project of Outstanding Young Teachers and Management Backbones, China(080318620081/037) ; Cross Training Programme for High Level Graduate in Beijing Universities, China(201507 ; Undergraduate Research Training Program, China(2016J00079) ; 201506)
WOS记录号WOS:000384967000023
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21621
专题生化工程国家重点实验室
作者单位1.Beijing Inst Petrochem Technol, Dept Chem Engn, Beijing 102617, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Yu Tian,Xu Chengnan,Yu Yuan,et al. Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2016,37(9):1740-1743.
APA Yu Tian.,Xu Chengnan.,Yu Yuan.,Zhao Feifei.,Pan Yiting.,...&Zhang Rongyue.(2016).Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,37(9),1740-1743.
MLA Yu Tian,et al."Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 37.9(2016):1740-1743.
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