Thermodynamics and phase equilibrium of the high concentration solid solution-aqueous solution system KCl-RbCl-H2O from T=298.15 K to T=323.15 K
Guo, Lijiang1,2; Han, Haijun1; Dong, Ouyang1; Yao, Yan1
2017-03-01
发表期刊JOURNAL OF CHEMICAL THERMODYNAMICS
ISSN0021-9614
卷号106页码:285-294
摘要Water activities of the high concentration solid solution-aqueous solution system (SS-AS) KCl-RbCIl-H2O and its sub-binary systems at T= 298.15 K and T=323.15 K have been elaborately measured by an isopiestic method. The solubility of this ternary system at T= (298.15, 308.15 and 323.15) K was also measured by a Flow-Cloud-Point method. A Pitzer model was used to estimate the reliability of the solubility reported in the literature, and to judge the type of solid phase, by correlating the measured water activity and the reported solubility values. The binary model parameters as a function of temperature between T=298.15 K and T=323.15 K were obtained by fitting the water activities in the binary systems. The predicted water activities at T=298.15 K and T= 323.15 K with the obtained binary parameters only, are in good agreement with the experimental values, which indicate that the Pitzer model can reliably represent the properties of the ternary system, with binary parameters only within the temperature range from T=298.15 K to T=323.15 K. Under the different assumptions that the equilibrium solid phase involved the pure salts (KCl(s) and RbCl(s) for the ideal solid solution or regular solid solution (K, Rb)Cl-(ss), the solubility isotherms at T= (298.15, 308.15 and 323.15) K were calculated and compared to experimental results, respectively. It was found that only the calculated solubility isotherms for (K, Rb)Cl-(ss) regular solid solution are consistent with the corresponding experimental values. The solid phase equilibrated with the aqueous solution in the KCI-RbCl-H2O ternary system should be a regular solid solution (K, Rb)Cl-(ss). This conclusion also can be verified from the Lippman log Sigma K-X-s - X-act and Phi Sigma(m) - X-s - X-aq equilibrium diagrams. (C) 2016 Elsevier Ltd.
关键词Solid Solution-aqueous Solution Water Activity Solubility Pitzer Model Potassium Chloride Rubidium Chloride
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.jct.2016.12.003
收录类别SCI
语种英语
关键词[WOS]ALKALI-HALIDE SYSTEMS ; TERNARY-SYSTEMS ; MINERAL SOLUBILITIES ; LIQUID EQUILIBRIUM ; DOUBLE SALTS ; WATER ; 25-DEGREES-C ; RUBIDIUM ; RB ; NA
WOS研究方向Thermodynamics ; Chemistry
WOS类目Thermodynamics ; Chemistry, Physical
项目资助者National Natural Science Foundation of China(21303239 ; Nature Science Foundation of Qinghai(2013-Z-927Q) ; 21406253)
WOS记录号WOS:000392352900031
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21902
专题湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Chinese Acad Sci, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China
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Guo, Lijiang,Han, Haijun,Dong, Ouyang,et al. Thermodynamics and phase equilibrium of the high concentration solid solution-aqueous solution system KCl-RbCl-H2O from T=298.15 K to T=323.15 K[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2017,106:285-294.
APA Guo, Lijiang,Han, Haijun,Dong, Ouyang,&Yao, Yan.(2017).Thermodynamics and phase equilibrium of the high concentration solid solution-aqueous solution system KCl-RbCl-H2O from T=298.15 K to T=323.15 K.JOURNAL OF CHEMICAL THERMODYNAMICS,106,285-294.
MLA Guo, Lijiang,et al."Thermodynamics and phase equilibrium of the high concentration solid solution-aqueous solution system KCl-RbCl-H2O from T=298.15 K to T=323.15 K".JOURNAL OF CHEMICAL THERMODYNAMICS 106(2017):285-294.
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