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Effect of Reactive Nanoclays on Performances of PMMA/Reactive Nanoclay Nanocomposites
Chen Shiwei1,2; Lu Xuchen1,3; Wang Tizhuang1; Pan Feng1; Zhang Zhimin1
2016-12-01
Source PublicationJOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION
ISSN1000-2413
Volume31Issue:6Pages:1193-1200
Abstract

PMMA/reactive nanoclay nanocomposites were prepared by emulsion polymerization using two different reactive nanoclays. X-ray diffraction (XRD) and thermogravimetric analysis (TGA) results confirmed that the reactive nanoclays, kaolinite and montmorillonite, were obtained by the silylation reaction and the double bonds were grafted onto the edges and surfaces of the nanoclays. The presence of reactive nanoclays could increase the average molecular weights, the glass transition temperatures (T-g) and improve the thermal properties of nanocomposite. The tensile properties, Young's modulus, and the aging properties of the nanocomposite films were also enhanced while the light transmittance decreased. Furthermore, the nanocomposites with the reactive kaolinite presented better performances than that with the reactive montmorillonite. Finally, the action mechanism of the reactive nanoclays to the performances of PMMA/reactive nanoclay nanocomposites was proposed.

KeywordNanoclay Emulsion Polymerization Nanocomposite Thermal Property Mechanical Property
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1007/s11595-016-1511-8
Indexed BySCI
Language英语
WOS KeywordSILICATE NANOCOMPOSITES ; POLYCARBONATE/CLAY NANOCOMPOSITES ; POLY(LACTIC ACID) ; KAOLINITE ; CLAY ; ORGANOCLAY ; POLYMERS ; FIRE
WOS Research AreaMaterials Science
WOS SubjectMaterials Science, Multidisciplinary
Funding OrganizationNational Youth Natural Science Foundation of China(21406247)
WOS IDWOS:000393051300003
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/21908
Collection多相复杂系统国家重点实验室
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.United Res Ctr Resource & Mat, Wuhai 016000, Peoples R China
Recommended Citation
GB/T 7714
Chen Shiwei,Lu Xuchen,Wang Tizhuang,et al. Effect of Reactive Nanoclays on Performances of PMMA/Reactive Nanoclay Nanocomposites[J]. JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION,2016,31(6):1193-1200.
APA Chen Shiwei,Lu Xuchen,Wang Tizhuang,Pan Feng,&Zhang Zhimin.(2016).Effect of Reactive Nanoclays on Performances of PMMA/Reactive Nanoclay Nanocomposites.JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION,31(6),1193-1200.
MLA Chen Shiwei,et al."Effect of Reactive Nanoclays on Performances of PMMA/Reactive Nanoclay Nanocomposites".JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION 31.6(2016):1193-1200.
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