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Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment
Liu, Xingcen1,4; Fei, Jinbo1; Wang, Anhe2; Cui, Wei1; Zhu, Pengli3; Li, Junbai1,4
2017-03-01
发表期刊ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
卷号56期号:10页码:2660-2663
摘要Controlled molecular assembly is an important approach for the synthesis of single-component materials with diverse functions. Unlike traditional heat treatment or solvent modulation, cryogenic treatment at 77 K enabled the tunable transition of a self-assembled diphenylalanine organogel into a hexagonal crystal. Under these conditions, the assembled molecules undergo an internal rearrangement in the solid state to form a well-defined chiral crystal structure. Moreover, these assemblies exhibit enhanced emission. This strategy for the synthesis of single-component supramolecular assemblies can create new functions by manipulating phase transitions.
关键词Cryogenic Treatment Crystalline Compounds Dipeptides Organogels Self-assembly
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1002/anie.201612024
收录类别SCI
语种英语
关键词[WOS]ASSEMBLED PEPTIDE NANOTUBES ; PHASE ; GELS ; TRANSITION ; SOLVENT ; CRYSTALLIZATION ; NANOSTRUCTURES ; GELATION ; MICROTUBES ; MOLECULES
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
项目资助者National Natural Science Foundation of China(21433010 ; National Basic Research Program of China (973 program)(2013CB932802) ; 21320102004 ; 21273250 ; 21573248 ; 21303219 ; 21003074)
WOS记录号WOS:000395183600018
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21949
专题生化工程国家重点实验室
作者单位1.Chinese Acad Sci, Inst Chem, BNLMS, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Liu, Xingcen,Fei, Jinbo,Wang, Anhe,et al. Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(10):2660-2663.
APA Liu, Xingcen,Fei, Jinbo,Wang, Anhe,Cui, Wei,Zhu, Pengli,&Li, Junbai.(2017).Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(10),2660-2663.
MLA Liu, Xingcen,et al."Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.10(2017):2660-2663.
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