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Rambutan-like hierarchically heterostructured CeO2-CuO hollow microspheres: Facile hydrothermal synthesis and applications
Ji, Yongjun1; Jin, Zheying1; Li, Jing1,2; Zhang, Yu1,2; Liu, Hezhi1; Shi, Laishun3; Zhong, Ziyi4,5; Su, Fabing1
2017-02-01
发表期刊NANO RESEARCH
ISSN1998-0124
卷号10期号:2页码:381-396
摘要Hierarchically heterostructured hollow spheres are of great interest for a wide range of applications owing to their unique structural features and properties. However, the fabrication of well-defined hollow spheres with highly specific morphology for mixed transition metal oxides on a large scale remains challenging. In this work, uniform rambutan-like heterostructured CeO2-CuO hollow microspheres with numerous copper-ceria interfacial sites and nanorods and nanoparticles as building blocks are prepared via a facile hydrothermal method followed by calcination. Importantly, this approach can be readily scaled up and is applicable to the synthesis of various CuO-based mixed metal oxide complex hollow spheres. The as-prepared CeO2-CuO hollow rambutans exhibit superior performance both as electrode materials for supercapacitors and as Cu-based catalysts for the Rochow reaction, mainly due to the small primary nanoparticle constituents, high surface area, and formation of numerous interior heterostructures.
关键词Heterostructure Hollow Sphere Rambutan Supercapacitors Rochow Reaction
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1007/s12274-016-1298-0
收录类别SCI
语种英语
关键词[WOS]LITHIUM STORAGE PROPERTIES ; TEMPLATE-FREE SYNTHESIS ; GAS-PHASE OXIDATION ; PREFERENTIAL OXIDATION ; ION BATTERIES ; SPHERES ; CATALYST ; CO ; COPPER ; NANOCRYSTALS
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
项目资助者National Natural Science Foundation of China(21506224 ; 51272252)
WOS记录号WOS:000394322300003
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/21954
专题多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
4.Inst Chem Engn & Sci, 1 Pesek Rd, Singapore 627833, Singapore
5.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore
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Ji, Yongjun,Jin, Zheying,Li, Jing,et al. Rambutan-like hierarchically heterostructured CeO2-CuO hollow microspheres: Facile hydrothermal synthesis and applications[J]. NANO RESEARCH,2017,10(2):381-396.
APA Ji, Yongjun.,Jin, Zheying.,Li, Jing.,Zhang, Yu.,Liu, Hezhi.,...&Su, Fabing.(2017).Rambutan-like hierarchically heterostructured CeO2-CuO hollow microspheres: Facile hydrothermal synthesis and applications.NANO RESEARCH,10(2),381-396.
MLA Ji, Yongjun,et al."Rambutan-like hierarchically heterostructured CeO2-CuO hollow microspheres: Facile hydrothermal synthesis and applications".NANO RESEARCH 10.2(2017):381-396.
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